ISSN:
0947-6539
Keywords:
electron microscopy
;
gels
;
helices
;
self-assembly
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis, molecular structure, and properties of a new chiral gelforming agent 1 are described. Key structural features in 1 are a γ-alkoxybutyro-lactone tetralin moiety and an angular phenylsulphone unit. The new low molecular weight gelator 1 can reversibly form stable gels in low concentrations (e.g., 1:800 for n-hexane) with isopropanol and a variety of apolar organic solvents. The gels were studied with differential scanning calorimetry and a combination of electron microscopy techniques, which revealed a highly ordered three-dimensional network of entangled fibers. X-ray analysis showed that the aggregation of 1 leads to a helical structure in the solid state. Nonchiral analogues 2 and 3 were unable to initiate gel formation.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/chem.19950010905
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