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  • Atomic, Molecular and Optical Physics  (3)
  • sedimentology  (1)
  • 1970-1974  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 4 (1972), S. 235-248 
    ISSN: 1573-8868
    Keywords: directional data analysis ; new statistical tests ; sampling ; statistics ; orientation data ; paleocurrent analysis ; sedimentology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Statistical procedures for (1) sampling, (2) testing the existence of a preferred direction, and (3) testing homogeneity of twodimensional directional data, which have been developed by the authors for paleocurrent studies, are presented. It is well known that conventional methods of statistical analysis are not applicable to directional data (e.g., crossbedding and ripplemark directions, grain lineations, etc.) which are “circularly distributed” on a compass dial. A sampling technique for directional data has been developed using the circular measures of dispersion and approximate ANOVA of G. S. Watson. On the basis of a pilot survey, it is possible to compute the minimum sample size required for estimating, with a desired precision, the mean paleocurrent direction of a formation. The optimum allocation of sample size between and within outcrops also can be accomplished at a minimum cost. The procedure described for testing uniformity (or lack of preferred direction) is based on the arc lengths made by successive sample points and is simple to use if the sample size is moderate. A table of critical points and a numerical example are given after a description of the test procedure. Finally, the procedures for testing the homogeneity of directional data from several geological formations are described by (1) tests for equality of the resultant directions (polar vectors) and (2) tests for equality of dispersions. With these tests it is possible to determine whether the paleocurrent directions from different geological formations belong to significantly different populations.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 4 (1970), S. 139-147 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In an earlier paper (Bibliography [1]) it has been shown that approximate representations of excited states of atoms can be obtained from the study of the singularities in the dynamic polarizability. Starting with these wave functions a more accurate calculation of the excited states in the Hartree-Fock scheme can be made by a perturbation treatment. The resulting wave functions yield significantly improved energy values. The 21P, 31P and 41P states of the He sequence up to C4+ are studied. The expectation values of a number of operators are calculated. The results obtained by the present method compare favourably with other elaborate calculations.
    Additional Material: 4 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 4 (1970), S. 465-486 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The quadrupolar and octupolar distortion of the ions in the He-sequence caused by an external electro-magnetic field has been studied by a variation-perturbation method in the Hartree-Fock scheme. For certain frequencies singularities appear in the response of the system to the perturbation. Approximate representations for the excited d and f states have been obtained from a study of these resonances. Such a perturbation calculation has the advantage that representations of the different excited states are obtained independently. The orthogonality to all the lower lying levels of the same symmetry is not required. The only source of inaccuracy implicit in the procedure lies in the improper consideration of the inter-electronic interaction. This is corrected for by an independent calculation, which is again formulated in terms of a perturbation treatment. The resulting wave functions for the excited states are accurate in the Hartree-Fock model. Expectation values of several operators have been calculated with these corrected wave functions.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 6 (1972), S. 337-345 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The variation perturbation method in the coupled Hartree-Fock (HF) scheme has been used to calculate the fourth-order energies of He, Li+ and Be2+ ions subjected to a uniform external electric field. The hyper-polarizabilities γh which are related to the fourthorder energies have been calculated neglecting intra-atomic correlation. For He the observed value is γh = 53.6 ± 4.0 a.u. The present estimate in the coupled and uncoupled HF schemes yield 36.2 and 45.3 a.u. respectively. The other calculations using correlated ground state wave function gave values in the range 42-44 a.u. The discrepancies between our result and those of others have been discussed.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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