ISSN:
1573-9171
Keywords:
resonant dissociative attachment
;
five-membered heteroaromatic compounds
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The thermochemistry of resonant dissociative electron attachment processes for furan, thiophene, selenophene, and pyrrole molecules has been studied. The structures of the dissociation products originating from negative molecular ions at energies ranging from 2 to 6 eV have been established using the measured appearance energies of fragment ions and the known thermodynamic functions of radical and molecular dissociation products. Heats of formation and electron affinities for some radicals and molecules have been assessed by calculations and estimated experimentally. It has been concluded that the majority of the fragment ions are formedvia rearrangement processes in molecular or fragment ions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01558063
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