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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 10 (1989), S. 701-712 
    ISSN: 1572-9567
    Keywords: gaseous mixtures ; R12 + R114 ; refrigerants ; R12 ; R113 ; R114 ; superheated and supercritical ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract New viscosity measurements for the gaseous and supercritical state of the halogenated hydrocarbons R12, R113, and R114 and binary mixtures of R12 + R114 of different compositions are presented. The measurements were carried out at superheated and supercritical temperatures from 30 to 200° C and in the pressure range from 1 to 80 bar. Viscosity was measured with an oscillating-disk viscometer and the data obtained are relative to the viscosity of nitrogen. The estimated accuracy of the measured results is ±0.6%. The results obtained show that, at subcritical temperatures, the pressure effect on viscosity is negative. This anomalous behaviour is investigated in detail in this work. At atmospheric pressure the viscosity of gas mixtures is almost a linear function of their composition. At high pressure, the residual viscosities η -η 0 of both the pure components and the mixtures were used to follow a single relationship versus the residual reduced density ρ r0.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 20 (1999), S. 777-790 
    ISSN: 1572-9567
    Keywords: gaseous ; R404A ; R407C ; R410A ; R507 ; refrigerants ; saturation ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper presents new measurements of the viscosity of gaseous R404A (52 wt% R143a, 44 wt% R125, 4 wt% R134a), R407C (23 wt% R32, 25 wt% R125, 52 wt% R143a), R410A (50 wt% R32, 50 wt% R125), and R507 (50 wt% R143a, 50 wt% R125). These mixtures are recommended as substitutes for the refrigerants R22, R502, and R13B1. Measurements were carried out in an oscillating-disk viscometer. The obtained values of the viscosity are relative to the viscosity of nitrogen. The experiments were performed at atmospheric pressure over the temperature range 297 to 403 K. and near the saturation line up to pressures of 0.6 P crit. The estimated uncertainty of the reported viscosities are ±0.5% for the viscosities at atmospheric pressure and ± 1% along the saturation line, being limited by the accuracy of the available vapor pressure and density data. The experimental viscosities at atmospheric pressure are employed to determine the intermolecular potential parameters, σ and ɛ, which provide the optimum representation of the data with the aid of the extended law of corresponding states developed by Kestin et al. A comparison of the experimental viscosity data with the values calculated by REFPROP, both at atmospheric pressure and along the saturation line, is presented.
    Type of Medium: Electronic Resource
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