ISSN:
0887-624X
Keywords:
polymethylphenylsilane
;
polymeric photoinitiator
;
rate constants
;
monomer dipole moment
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The rates of photochemical polymerization of styrene (St), p-chlorostyrene (Cl-St), methyl methacrylate (MMA), and butyl methacrylate (BMA) with polymethylphenylsilane (PMPS) as an initiator were measured. Polymethylphenylsilane is photodegrated to form silyl radicals that may initiate polymerization of vinyl monomers. Rate constants kp and kt have been determined for these systems. A good correlation (log P = α + βμ) of the resonance stabilization (P) of the chain radicals and the dipole moment (μ) of the monomers is observed for these polymerization systems. This equation may be used to estimate the resonance stabilization (P) of a monomer and the polymerization rate constant (kp). © 1996 John Wiley & Sons, Inc.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
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