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Rate constants for addition of phenoxyl radicals to the vinyl monomer double bond (1992)

Utkin, I. V. ; Sokolov, A. V. ; Pliss, E. M.

Springer

Russian chemical bulletin 41 (1992), S. 2147-2151

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ISSN: 1573-9171

Keywords: vinyl monomers ; radical oxidation ; inhibitors ; phenols ; reactivity ; kinetics

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Rate constants were measured for the addition of the 2,4,6-tri(tert-butyl)phenoxyl radical (logk 10, [liter/(mole · sec)]) to the double bond of styrene (9.73 − 4621/T), methyl methacrylate (10.1 − 4972.7/T) and butylacrylate (7.68 − 4313.9/T); and for addition of the 2,4,6-tribromophenoxyl radical to styrene (k 10=0.5;T=323 K). A simulation based on these constants for the inhibited oxidation of styrene under conditions similar to those of monomer storage demonstrated the need to take account of this reaction when analyzing kinetic schemes describing the inhibited oxidation process.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01150736

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