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  • 1
    Electronic Resource
    Electronic Resource
    Neue Fluoropalladate(II) M2[PdF4] (M = Na, K) sowie K2RbPdF5Professor Hanskarl Müller-Buschbaum zum 60. Geburtstag (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 597 (1991), S. 9-18 
    Details
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladate(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Fluoropalladates(II) M2[PdF4] (M = Na, K) and K2RbPdF5For the first time bright yellow single crystals M2[PdF4] (M = Na, K) have been obtained and their structure determined. K2[PdF4] crystallizes monoclinic, space group C2/m-C2h3 (No. 12) with a = 975.2(3) pm, b = 597.6(1) pm, c = 420.2(1) pm, β = 92.17(2)° and Z = 2. Structure related Na2[PdF4] crystallizes monoclinic too, but in space group P21/c-C2h5 (No. 14) with a = 340.88(7) pm, b = 561.1(1) pm, c = 999.2(2) pm, β = 93.97(2)° and Z = 2. K2RbPdF5, yellow, crystallizes tetragonal with a = 724.9(1) pm, c = 627.9(1) pm, Z = 2 and is isotypic with Rb2CsPdF5 (space group P4/mbm-D4h5, No. 127), an ordered structure variant of the Rb3PdF5-type [1].
    Notes: Erstmals konnten leuchtend gelbe Einkristalle M2[PdF4] (M = Na, K) dargestellt und ihre Struktur bestimmt werden. K2[PdF4] kristallisiert monoklin, R.G. C2/m-C32h (Nr. 12) mit a = 975,2(3) pm, b = 597,6(1) pm, c = 420,2(1) pm, β = 92,17(2)° und Z = 2. Strukturverwandtes Na2[PdF4] kristallisiert ebenfalls monoklin, jedoch in der R.G. P21/c-C2h5 (Nr. 14) mit a = 340,88(7) pm, b = 561,1(1) pm, c = 999,2(2) pm, β = 93,97(2)°und Z = 2. K2RbPdF5, gelb, kristallisiert tetragonal mit a = 724,9(1) pm, c = 627,9(1) pm, Z = 2 und ist isotyp zu Rb2CsPdF5 (R.G. P4/mbm-D4h5, Nr. 127), einer geordneten Strukturvarianten des Rb3PdF5-Typs [1].
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19915970103
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  • 2
    Electronic Resource
    Electronic Resource
    Darstellung und Struktur der Tetrafluoroaurate(III) MI[AuF4] mit MI = Li, RbProfessor Hans Georg von Schnering zum 60. Geburtstage gewidmet (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 598 (1991), S. 103-110 
    Details
    ISSN: 0044-2313
    Keywords: Lithium, rubidium tetrafluoroaurate(III) ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Tetrafluoroaurates(III) MI[AuF4] with MI = Li, RbSingle crystal investigations on Rb[AuF4], light yellow, confirm the tetragonal unit cell (K[BrF4]-type) with a = 618.2(1) and c = 1191(1) pm, Z = 4, space group I 4/mcm-D4h18 (No. 140).Li[AuF4], light yellow too, crystallizes monoclinic with a = 485.32(7), b = 634.29(8), c = 1004.43(13) pm, β = 92.759(12), Z = 4; space group P 2/c-C2h4 (No. 13). The structure of Li[AuF4] is related to the Rb[AuF4]-type of structure.
    Notes: Einkristalluntersuchungen an Rb[AuF4], hellgelb, bestätigen die tetragonale Elementarzelle (K[BrF4]-Typ) mit a = 618,2(1) und c = 1191(1) pm, Z = 4, Raumgruppe I 4/mcm-D4h18 (Nr. 140).Ebenfalls hellgelbes Li[AuF4] hingegen kristallisiert monoklin (eigener Typ) in der Raumgruppe P 2/c-C2h4 (Nr. 13) mit a = 485,32(7), b = 634,29(8), c = 1004,43(13) pm, β = 92,759(12), Z = 4 und ist mit der Rb[AuF4]-Struktur verwandt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19915980110
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  • 3
    Electronic Resource
    Electronic Resource
    Tetrafluoroaurate(III) der Lanthaniden MF[AuF4]2 (M = Tm, Yb, Lu) (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1661-1668 
    Details
    ISSN: 0044-2313
    Keywords: Rare earth tetrafluoroaurates(III) ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tetrafluoroaurates(III) of Lanthanides MF[AuF4]2 (M = Tm, Yb, Lu).Tetrafluoroaurates(III) MF[AuF4]2 with M = Tm, Yb, Lu, all yellow, have been prepared for the first time. From single crystal data they crystallize orthorhombic, space group Pbcn-D2h14 (No. 60) with M = Tm: a = 1 102.92(8) pm, b = 904.38(8) pm, c = 2 164.46(23) pm; M = Yb: a = 1 100.98(12) pm, b = 902.23(8) pm, c = 2 157.36(23) pm; M = Lu: a = 1 099.28(18) pm, b = 900.70(15) pm, c = 2 151.50(46) pm.
    Notes: Neu dargestellt wurden gelbe Tetrafluoroaurate(III) der Lanthaniden MF[AuF4]2 mit M = Tm, Yb, Lu. Nach Einkristalluntersuchungen kristallisieren diese orthorhombisch in der Raumgruppe Pbcn-D2h14 (Nr. 60) mit Z = 12. Im Einzelnen wurden folgende Werte gefunden: Für M = Tm: a = 1 102,92(8) pm, b = 904,38(8) pm, c = 2 164,46(23) pm; M = Yb: a = 1 100,98(12) pm, b = 902,23(8) pm, c = 2 157,36(23) pm; M = Lu: a = 1 099,28(18) pm, b = 900,70(15) pm, c = 2 151,50(46) pm.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936191004
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  • 4
    Electronic Resource
    Electronic Resource
    Fluoroplatinate(IV) der Lanthaniden LnF[PtF6]. (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er) (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1431-1440 
    Details
    ISSN: 0044-2313
    Keywords: Fluoroplatinates(IV) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fluoroplatinates(IV) of the Lanthanides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er)For the first time fluorides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), all yellow have been obtained. From single crystal data they crystallize monoclinic, space group P21/n-C2h5 (No. 14), Z = 4, Pr: a = 1 125.77(19) pm, b = 559.04(7) pm, c = 910.27(17) pm, β = 107.29(1)°; Sm: a = 1 114.63(31) pm, b = 552.70(12) pm, c = 898.02(20) pm, β = 107.24(2)°; Gd: a = 1 112.12(15) pm, b = 551.22(7) pm, c = 891.99(11) pm, β = 107.09(1)°; Tb (Powder data): a = 1 108.88(20) pm, b = 552.71(9) pm, c = 889.56(16) pm, β = 107.30(1)°; Dy: a = 1 100.28(23) pm, b = 547.77(8) pm, c = 882.41(13) pm, β = 107.32(1); Ho: a = 1 099.11(16) pm, b = 546.16(7) pm, c = 879.45(15) pm, β = 107.34(1)°; Er: a = 1 095.10(16) pm, b = 544.82(10) pm, c = 874.85(14) pm, β = 107.37(1)°.
    Notes: Erstmals dargestellt wurden Fluoride LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), alle gelb. Nach Einkristalluntersuchungen kristallisieren diese monoklin in der Raumgruppe P21/n-C2h5 (Nr. 14), Z = 4, Pr: a = 1 125,77(19) pm, b = 559,04(7) pm, c = 910,27(17) pm, β = 107,29(1)°; Sm: a = 1 114,63(31) pm, b = 552,70(12) pm, c = 898,02(20) pm, β = 107,24(2)°; Gd: a = 1 112,12(15) pm, b = 551,22(7) pm, c = 891,99(11) pm, β = 107,09(1)°; Tb (Pulverdaten): a = 1 108,88(20) pm, b = 552,71(9) pm, c = 889,56(16) pm, β = 107,30(1)°; Dy: 1 100,28(23) pm, b = 547,77(8) pm, c = 882,41(13) pm, β = 107,32(1)°; Ho: a = 1 099,11(16) pm, b = 546,16(7) pm, c = 879,45(15) pm, β = 107,34(1)°; Er: a = 1 095,10(16) pm, b = 544,82(10) pm, c = 874,85(14) pm, β = 107,37(1)°. Im Gegensatz zu älteren Befunden liegt die Raumgruppe P21/n-C2h5 (Nr. 14) mit einem verdoppelten Zellvolumen vor.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936190819
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  • 5
    Electronic Resource
    Electronic Resource
    Über Komplexe Fluoride des zweiwertigen PalladiumsProfessor Rudolf Hoppe zum 70. Geburtstage gewidmet (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 7-13 
    Details
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Complex Fluorides of Divalent PalladiumFor the first time single crystals of the new compounds RbPdPdF5, KPdPdF5, and K2CsPdF5 have been obtained. Orange brown RbPdPdF5 crystallizes orthorhombic, space group Imma-D2h28 (No. 74) with a = 633.6(1) pm, b = 765.5.(1) pm, c = 1067.5(1) pm and Z = 4 and is isotypic with CsPdPdF5 [1]. Structure related KPdPdF5 (also orange brown) crystallizes orthorhombic too, but in space group Pnma-D2h16 (No. 62) with a 614.12(9) pm, b = 748.7(1) pm, c = 1065.0(2) pm and Z = 4. K2CsPdF5, light yellow, crystallizes tetragonal with a = 736.3(1) pm, c = 628.0(1) pm, Z = 2, and is isotypic with Rb2CsPdF5 (space group P4/mbm—D4h5 Nr. 127), an ordered structure variant of the Rb3PdF5-Type [1].
    Notes: Neu dargestellt wurden RbPdPdF5, KPdPdF5 und K2CsPdF5, alle in Form von Einkristallen. Orangebraunes RbPdPdF5 kristallisiert orthorhombisch, R. G. Imma-D2h28 (Nr. 74) mit a = 633,6(1) pm, b = 765,5(1) pm, c = 1067,5(1) pm und Z = 4 und ist isotyp zu CsPdPdF5 [1]. Strukturverwandtes KPdPdF5 (ebenfalls orange-braun) kristallisiert gleichfalls orthorhombisch, jedoch in der R. G. Pma—D2h16 (Nr. 62) mit a = 614,12(9) pm, b = 748,7(1) pm, c = 1065,0(2) pm und Z = 4. K2CsPdF5, hellgelb, kristallisiert tetragonal mit a = 736,3(1) pm, c = 628,0(1) pm Z = 2, ist isotyp zu Rb2CsPdF5 (R. G. P4/mbm—D4h5) (Nr. 127) und somit ein weiterer Vertreter der geordneten Strukturvariante des Rb3PdF5-Typs [1].
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926161002
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  • 6
    Electronic Resource
    Electronic Resource
    LiSmAlF6  -  das erste Fluoroaluminat mit zweiwertigem Samarium (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 606 (1991), S. 169-176 
    Details
    ISSN: 0044-2313
    Keywords: Lithium samarium hexafluoroaluminate ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: LiSmAlF6  -  the First Fluoroaluminate with Divalent SamariumLiSmAlF6, the first quaternary fluoride with Sm2+ that has been obtained as red transparent single crystals, is formed while heating corresponding mixtures of the starting materials in niobium or tantalum crucibles under argon after 7-10 d at about 800°C. Orange-red, microcrystalline powder samples of LiSmAlF6 could be prepared at T ≤ 700°C after 1-2 d under the same conditions.LiSmAlF6, crystallizes as a new structure type in P6322 (Nr. 182) with a = 507.9(1), c = 1 040.5(1) pm and Z = 2 (CAD4, 2 512 Io, Rw = 2,3%). The crystal structure of LiSmAlF6 is related to the LiCaAlF6 structure type whereby the essential difference lies in the coordination of the M2+ ions. Ca2+, as well as Sr2+ in LiSrAlF6, exhibit octahedral coordination, whereas Sm2+ has, surprisingly, trigonal prismatic coordination to F-. The two triangles of the SmF6 prism are twisted by 8.3° with respect to each other.Measurements of the magnetic susceptibility show the temperature dependence typically found for Sm2+. The Madelung part of the lattice energy has been calculated and is discussed.
    Notes: LiSmAlF6, das erste in Form roter, transparenter Einkristalle erhaltene quaternäre Fluorid mit Sm2+, bildet sich beim Erhitzen geeigneter Ausgangsmenge in Niob- oder Tantaltiegln unter Ar nach 7-10 d bei ca. 800°C. Orangerote, mikrokristalline Pulverproben von LiSmAlF6 können bei T ≤ 700°C bereits nach 1-2 Tagen unter sonst gleichen Bedingungen dargestellt werden.LiSmAlF6 kristallisiert in einem neuen Strukturtyp in P6322 (Nr. 182) mit a = 507,9(1), c = 1 040,5(1) pm und Z = 2(CAD4, 2 512 Io, Rw = 2,3%). Die Kristallstruktur von LiSmAlF6 ist dem LiCaAlF6-Typ verwandt, zeigt aber den wesentlichen Unterschied in der Umgebung für M2+ : Ca2+, wie auch Sr2+ in LiSrAlF6, werden oktaedrisch, Sm2+ jedoch überraschenderweise trigonal-prismatisch von F- koordiniert. Die beiden Dreiecke des SmF6-Prismas sind um 8,3° gegeneinander verdreht.Messungen der magnetischen Suszeptibilität zeigen die für Sm2+ typische Temperaturabhängigkeit. Der Madelunganteil der Gitterenergie wurde berechnet und diskutiert.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19916060117
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  • 7
    Electronic Resource
    Electronic Resource
    Zur Synthese und Kristallstruktur von LiPdAlF6 und PdZrF6 (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 189-192 
    Details
    ISSN: 0044-2313
    Keywords: Fluoropalladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Crystal Structure of LiPdAlF6 and PdZrF6.For the first time single crystals of the new compounds LiPdAlF6 and PdZrF6 have been obtained. LiPdAlF6 (blue) crystallizes trigonal, space group P31c - D3d2 (No. 163; LiCaAlF6-type [2]), in an ordered structure variant of the Li2[ZrF6]-structure [3], with a=497.21(9) pm, c=914.0(9) pm and Z=2. PdZrF6 (also blue) is isotypic with LiSbF6 [4] and crystallizes trigonal-rhomboedric with a=552,3(1) pm, c=1 447,5(4) pm, space group R 3 - C3i2 (No. 148) and Z=3.
    Notes: Neu dargestellt wurden LiPdAlF6 und PdZrF6, beide in Form von Einkristallen. Blaues LiPdAlF6 kristallisiert trigonal im LiCaAlF6-Typ [2], einer Ordnungsvariante der Li2[ZrF6]-Struktur [3], in der Raumgruppe P31c - D3d2 (Nr. 163) mit a=497,21(9) pm, c=914,0(9) pm und Z=2. PdZrF6 (hellblau) kristallisiert trigonal-rhomboedrisch in der Raumgruppe R 3 - C3i2(Nr. 148) mit a=552,3(1) pm, c=1 447,5(4) pm und Z=3 (isotyp zu LiSbF6 [4]).
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936190131
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  • 8
    Electronic Resource
    Electronic Resource
    Einkristalluntersuchungen an Fluoroperowskiten MPdF3 (M = Rb, K) und PdF2 (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 387-391 
    Details
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Single Crystal Investigations on Fluoroperovskites MPdF3 (M = Rb, K) and PdF2Single crystal investigations on PdF2 (violet) confirm the tetragonale rutile structure [1, 2] with a = 495.44(3) pm, c = 338.48(3) pm, Z = 2, space group P42/mnm-D4h14 (No. 136) (xF = 0.3058(8)). RbPdF3 and KPdF3 have been obtained. RbPdF3 and KPdF3 both ruby-red single crystals crystallize cubic (perovskite-structure), space group Pm3m-Oh1 (No. 221) with a = 429.41(8) pm (RbPdF3) respectively a = 424.30(4) pm (KPdF3).
    Notes: Einkristalluntersuchungen an PdF2 (amethystfarben) bestätigen die Rutilstruktur [1, 2] mit a = 495,44(3) pm, c = 338,48(3) pm, Z = 2, Raumgruppe P42/mnm-D4h14 (Nr. 136) (xF = 0,3058(8)). RbPdF3 und KPdF3 (beides rubinrote Einkristalle) kristallisieren in der kubischen Perowskitstruktur, Raumgruppe Pm3m-Oh1 (Nr. 221) mit a = 429,41(8) pm (RbPdF3) bzw. a = 424,30(4) pm (KPdF3).
    Additional Material: 8 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936190225
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  • 9
    Electronic Resource
    Electronic Resource
    CsTi8F33 - nach (O2)2Ti7F30 der letzte Zwischenschritt zur TiF4-Struktur? (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1223-1226 
    Details
    ISSN: 0044-2313
    Keywords: Fluorotitanates(IV) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: CsTi8F33 - the Last Step on the Way to TiF4CsTi8F33 has been prepared for the first time as a byproduct of the synthesis of TiF4. The colourless compound crystallizes trigonal in the spacegroup P31c-C3v4 (No. 159) with a = 862 pm, c = 1 902 pm and Z = 2.
    Notes: CsTi8F33 wurde erstmals in Form farbloser, transparenter Einkristalle als Nebenprodukt bei Versuchen zur Darstellung von TiF4-Einkristallen [1] erhalten. Es kristallisiert trigonal in der nicht zentrosymmetrischen Raumgruppe P31c-C3v4 (Nr. 159) mit a = 862 pm, c = 1 902 pm und Z = 2.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210719
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