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  • 1
    Electronic Resource
    Electronic Resource
    Polysoaps with fluorocarbon hydrophobic chains (1995)
    Springer
    Colloid & polymer science 273 (1995), S. 1138-1143 
    Details
    ISSN: 1435-1536
    Keywords: Amphiphilic polymers ; fluorocarbon polymers ; associating polymers ; polysoaps
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A series of amphiphilic copolymers is prepared by copolymerization of choline methacrylate with 1,1,2,2-tetrahydroperfluorooctyl methacrylate in varying amounts. The copolymers bearing fluorocarbon chains are studied concerning their effects on viscosity, solubilization and surface activity in aqueous solution, exhibiting a general behavior characteristic for polysoaps. The results are compared with the ones obtained for an analogous series of amphiphilic copolymers bearing hydrocarbon chains.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00653081
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  • 2
    Electronic Resource
    Electronic Resource
    Solubilization by polysoaps (1994)
    Springer
    Colloid & polymer science 272 (1994), S. 1118-1128 
    Details
    ISSN: 1435-1536
    Keywords: Micellar polymers ; polysoaps ; solubilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The aqueous solubilization power of several series of micellar homopolymers and copolymers (“polysoaps”) is investigated. Using five insoluble or poorly water-soluble dyes, comparisons of the capacities are made with respect ot the influence of structural variables such as the polymer backbone, the polymer geometry, the comonomer content, and the charge of the hydrophilic group. Some guidelines for polysoap structures suited for efficient solubilization are established. Noteworthy is that the solubilization capacities of the polysoaps are neither linked to the ability to reduce the surface tension of water, nor to the polarity of the solubilization sites deduced from spectroscopic probes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00652381
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    Paper (German National Licenses)
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