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  • 1
    ISSN: 1573-1561
    Keywords: Philantus ; beewolf ; Sphecidae ; Hymenoptera ; pheromones ; scentmarking ; tridecanone ; pentadecanone ; heptadecanone ; hexadecanoic acid ; ethyl hexadecanoate ; octadecanoic acid ; ethyl octadecanoate ; mandibular glands ; wasps
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Observations of wasp behavior indicate that male beewolves,Philanthus basilaris andP. bicinctus apply a “marking pheromone” to the leaves and stems of plants within their territories. We now provide direct evidence for the presence of volatile chemicals in the paired mandibular glands of the males, provide preliminary identification of these volatiles, and show that all of the volatile chemicals in the mandibular glands are present on freshly marked plant surfaces but are absent from unmarked plants. Pyrazines, which have been reported in other species of aculeate wasps including the EuropeanPhilanthus triangulum, were not found inP. basilaris orP. bicinctus.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: Philanthus crabroniformis ; Philanthus barbatus ; Philanthus pulcher ; Hymenoptera ; Sphecidae ; beewolf ; mandibular glands ; pheromones ; semiochemicals ; mass spectrometry ; infrared spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The composition of the territorial marking pheromones from mandibular glands of males of the beewolvesPhilanthus crabroniformis, P. barbatus, andP. pulcher have been determined. The structures of the components were elucidated by gas chromatography-mass spectrometry and gas chromatography-Fourier transform infrared spectroscopy. The major compound ofP. crabroniformis is isopropyl tetradecanoate, with somewhat lesser amounts of 2-tridecanone, 3-methyl-3-butenyl tetradecanoate, and 92∶8 (Z)∶(E)-11-eicosen-1-ol. The major compounds ofP. barbatus are ethyl tetradecanoate and hexadecanal, which are present in approximately a 60∶40 ratio. These two compounds comprise over 95% of the neutral lipids. Also present in lesser amounts are ethyl dodecanoate, tetradecanal, hexadecan-1-ol, a Δ x -octadecen-1-ol, and octadecan-1-ol. The major compounds ofP. pulcher are ethyl (Z)-7-hexadecenoate and geranylgeraniol acetate, which comprise nearly 90% of the neutral lipid fraction, with smaller amounts of tetradecanal, pentadecanal, and ethyl hexadecanoate; trace amounts of Δ x hexadecenal, hexadecanal, and octadecanal are also present.
    Type of Medium: Electronic Resource
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