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  • Chemistry  (33)
  • pVT  (3)
  • Computer Systems
  • 1985-1989  (29)
  • 1975-1979  (5)
  • 1925-1929  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Measurement of the compressibility and sound velocity of helium up to 1 GPa (1988)
    Springer
    International journal of thermophysics 9 (1988), S. 425-438 
    Details
    ISSN: 1572-9567
    Keywords: adiabatic compressibility ; equation of state ; density ; high pressure ; isothermal compressibility ; helium ; pVT ; sound velocity ; ultrasonics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract By using a gas expansion technique, the density of helium has been determined at 298.15 K as a function of pressure from 100 MPa to 1 GPa. The precision of the measurements is 0.02%, while the estimated absolute accuracy is about 0.08%. The sound velocity has been measured by a phase-comparison pulseecho technique between 98 and 298 K with intervals of 25 K and at pressures up to 1 GPa, with an accuracy generally better than 0.04%. By combining pVT with velocity-of-sound data at 298 K, the adiabatic compressibility and the ratio of the specific heats are calculated. The experimental sound velocities are compared with the values, predicted from an equation of state as proposed by Hansen.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00513081
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  • 2
    Electronic Resource
    Electronic Resource
    Compressibility and sound velocity measurements on N2 up to 1 GPa (1988)
    Springer
    International journal of thermophysics 9 (1988), S. 103-116 
    Details
    ISSN: 1572-9567
    Keywords: adiabatic compressibility ; equation of state ; density ; high pressure ; isothermal compressibility ; nitrogen ; pVT ; sound velocity ; ultrasonics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A gas expansion technique has been used to determine the pVT properties of N2 up to 1 GPa at 298.15 K, with an accuracy of 0.08% in density, 1 mK in temperature, and 0.05%+0.2 MPa in pressure. The sound velocity has been measured by a phase-comparison pulse-echo technique between 123 and 298 K at intervals of 25 K and at pressures up to 1 GPa, with an accuracy of better than 0.02% in sound velocity, 10 mK in temperature, and 0.05%+0.2 MPa in pressure. An equation of state is presented that correlates the density data over the wide pressure range of 36–1000 MPa with maximum deviations between the calculated and the experimental densities of less than 0.05%.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00504003
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  • 3
    Electronic Resource
    Electronic Resource
    Measurement of the compressibility and sound velocity of neon up to 1 GPa (1988)
    Springer
    International journal of thermophysics 9 (1988), S. 803-812 
    Details
    ISSN: 1572-9567
    Keywords: compressibility ; equation of state ; high pressure ; neon ; pVT ; sound velocity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The density of neon has been determined at 298.15 K as a function of pressure from 80 MPa to 1 GPa. The precision of the measurements is 0.03%, while the estimated absolute accuracy is between 0.05 and 0.09%. The sound velocity has been measured between 98 and 298 K with intervals of 25 K and at pressures up to 1 GPa, with an accuracy generally better than 0.06%. The adiabatic compressibility and the ratio of the specific heats are calculated by combining pVT with velocity-of-sound data at 298 K. Several equations of state are fitted to the density data at 298.15 K.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00503246
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  • 4
    Electronic Resource
    Electronic Resource
    Stratified flow model for two-phase pressure drop prediction in trickle beds (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 510-513 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340321
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  • 5
    Electronic Resource
    Electronic Resource
    Importance of finite adsorption rate in the evaluation of adsorption and diffusion parameters in porous catalysts (1986)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 493-496 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690320316
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  • 6
    Electronic Resource
    Electronic Resource
    Chemiluminescenz bei der Oxydation von Farbstoffen durch Ozon (1928)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 173 (1928), S. 125-136 
    Details
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Wenn ozonisierter Sauerstoff durch Lösungen von Eosin, Uranin, Safranin, Neutralrot, Rhodamin B, Thioflavin, Cartharamin Rhodamin B. J. N. N., Erythrosin und Aesculin geleitet wird, beobachtet man ein Leuchten.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19281730114
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  • 7
    Electronic Resource
    Electronic Resource
    Chemiluminescenz bei der Oxydation von fluorescierenden und nicht fluorescierenden Stoffen durch Wasserstoffperoxyd und Ozon (1929)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 186 (1929), S. 154-158 
    Details
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Wenn zahlreiche fluorescierende oder nicht fluorescierende Farbstofflösungen durch Wasserstoffperoxyd in Gegenwart von Ferrosulfat oxydiert werden, tritt ein Glimmen auf, das im dunklen Raume zu erkennen ist.2. Die Wellenlangen der Glimmerscheinung bei der Oxydation einiger fluorescierender Fnrbstoffe durch ozonisierten Sauerstoff sind gemessen worden.3. Kieselsaure mit etwas adsorbiertem Neutralrot zeigt in einer Suspension in Äthylallrohol bei Behandlung mit ozonisiertem Sauerstoff eine Glimmerscheinung.4. Wenn kleine Mengen eines Farbstoffes, der gutes Glimmen zeigt , rnit einem anderen Farbstoff von schwachem Glimmvermogen gemischt werden, so liefert das Gemisch bei Behandlung mit Ozon ein starkeres Glimmen als der schwächer glimmende Farbstoff allein.5. Steigerung der Temperatur führt zur Verstarkung des Glimmens bei der Oxydation von Reduktionsmitteln durch Ozon oder Wasserstoffperoxyd.6. Zunahme der Konzentration der Reduktionsmittel verursacht eine Steigerung der Glimmintensitat bis zu einem Grenewert. Wird die Konzentration weiter gesteigert, so schwacht sich das Glimmen ab und hört schließlich auf.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19291860111
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  • 8
    Electronic Resource
    Electronic Resource
    A cation exchange resin from poly(N-vinyl carbazole) (1978)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 72 (1978), S. 57-66 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(N-vinylcarbazol) wurde mit verschiedenen Reagenzien sulfoniert und die Ionenaustauschkapazität der erhaltenen Harze bestimmt. Eine maximale Kapazität von 4,5 meq · g-1 des trockenen Harzes wurde durch 10stündige Reaktion mit 98,8proz. H2SO4 bei 30°C erhalten. Die pH-Titrationskurven lassen einen starken monofunktionellen Kationenaustauscher mit einem pK-Wert von 2,2 erkennen. Das Harz zeigt eine mäßige Austauschgeschwindigkeit mit NaCl und ist bis zu 250°C thermisch stabil.
    Notes: Poly(N-vinyl carbazole) was sulfonated with different sulfonating agents and ion exchange capacities of the resins produced were evaluated. A maximum capacity of 4.5 meq · g-1 of dry resin was realized when sulfonation was done with 98.8% H2SO4 at 30°C for 10 h. The pH titration curves reveal the nature of a strong monofunctional cation exchanger with a pK value of 2.2. The resin exhibits a moderate rate of exchange with NaCl and is thermally stable up to ca. 250°C.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1978.050720105
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  • 9
    Electronic Resource
    Electronic Resource
    A cation exchange resin based on the condensation product of poly(iso-butyl vinyl ether) and furfural (1978)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 73 (1978), S. 53-61 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Kationenaustauscher wurde durch Kondensation von Polyisobutylvinyläther und Furfural hergestellt. Als Katalysator diente konzentrierte Schwefelsäure. Der Austauscher wurde durch Messen der Austauschkapazität, durch Untersuchen seiner thermischen Belastbarkeit und durch Bestimmen seines Verhaltens bei der pH-Titration charakterisiert. Es scheint sich um einen Austauscher mit schwachen Säregruppen zu handlen, die wohl als —COOH-Gruppen vorliegen und durch Oxidation aus den Furfuralgruppen entstanden sein dürften.
    Notes: A cation exchange resin was synthesized from the condensation product of poly(iso-butyl vinyl ether) and furfural by treating it with concentration sulphuric acid. The resin produced was characterized by measuring its total and salt splitting capacities, and by studying its thermal characteristics and behaviour to pH metric titration. The latter suggests the resin to be a weak one possibly containing —COOH groups, which result from the oxidation of the furfural aldehyde group by sulphuric acid.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1978.050730104
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  • 10
    Electronic Resource
    Electronic Resource
    Vinyl polymerization by carbon black, IV. Some properties of modified carbon black compared with its polymerization initiating activity (1985)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 129 (1985), S. 43-59 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Alle Arten von Ruß enthalten große Anteile an ungepaarten Elektronen und organischen funktionellen Gruppen. Die Polymerisation wird wahrscheinlich durch die ungepaarten Elektronen auf der Oberfläche ausgelöst; die funktionellen Gruppen haben auf die auslösende Reaktion einen Promotor-Effekt. Alle Eigenschaften wie Textur, Geometrie, Größe der Oberfläche, pH der wäßrigen Aufschlämmung, Aschegehalt und elementare Zusammensetzung haben Einfluß auf die Polymerisation. Diese einschlägigen physikochemischen und Oberflächen-Eigenschaften von nicht modifiziertem und modifiziertem Ruß N 220 wurden im Hinblick auf die Polymerisation von N-Vinylcarbazol untersucht.
    Notes: All grades of carbon black contain large amounts of unpaired electrons and organic functional groups. Polymerization reaction is possibly initiated by the unpaired electrons on the surface; the functional groups have promotional effect on the initiation process. All the properties like texture, geometry, surface area, pH of the aqueous slurry, ash content, and elemental composition have effects on the polymerization reaction. These pertinent physicochemical and surface properties of unmodified and modified N 220 carbon black have been studied in relation to N-vinylcarbazole polymerization.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1985.051290104
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