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  • nucleation and crystallization of WO3  (1)
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    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 157-166 
    ISSN: 1572-8943
    Keywords: nucleation and crystallization of WO3 ; WO3
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract DTA runs and flux growth experiments have shown that the crystallization temperatures of WO3 from NaF flux are in the range of 1020–1090°C. Addition of Pb2+ influences the crystal growth and the crystallization temperatures are altered (within this range). A thermal effect giving rise to an exothermal DTA peak was observed above the crystallization temperature. This peak occurs at a higher temperature when lead ions are present. We propose an explanation based on pre-crystallization clustering and on the number of nucleation sites on the surface of the platinum crucible.
    Type of Medium: Electronic Resource
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