ISSN:
1573-9171
Keywords:
paramagnetic birefringence
;
molecular mechanics
;
dysprosium, complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The molar constants of paramagnetic birefringence (PBR) for the dimeric dysprosium(iii)d- anddl-tartrates, Dy2(d-Tart)(l-Tart)2− (1) and Dy2(d-Tart)2 2− (2) have been determined by means of pH-metric and PBR measurements. The simulation of the structure of the ligand and solvate environment has been carried out using the method of molecular mechanics (Dashevsky-Plyamovaty model, the MIND program). In addition to the four oxygen atoms from the ligand, each DyIII ion coordinates four molecules of water and a Na+ ion.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01558058
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