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  • 1
    Publication Date: 2017-04-04
    Description: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 2
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated in 19 t/a. Contemporaneous CO2 flux measurements showed a fair positive correlation between CO2 and CH4 fluxes but the flux ratio evidenced methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. These results further confirm recent studies on other geothermal systems that revealed the existence of thermophilic and acidophilic bacteria exerting methanotrophic activity also in hot and acid soils thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: Thessaloniki, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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