ISSN:
1573-1111
Schlagwort(e):
Hofmann-type clathrate
;
metal-imidazole complexes
;
dioxane inclusion compounds
;
IR and Raman spectra
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract Four new clathrates of the formula M(Im)2Ni(CN)4·2·Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1007941906692
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