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  • 1
    Electronic Resource
    Electronic Resource
    Soil solution chemistry of two reclamation sites in the Lusatian lignite mining district as influenced by organic matter application (1999)
    Springer
    Plant and soil 213 (1999), S. 231-240 
    Details
    ISSN: 1573-5036
    Keywords: compost ; fly ash ; lignite ; minesite reclamation ; sewage sludge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Due to a large reclamation (recultivation) demand in the Lusatian lignite mining district, efficient strategies for the rehabilitation of abandoned mine sites are needed. A field study was conducted for comparing the effects of three different fertilizer treatments (mineral fertilizer, sewage sludge and compost) on soil solution chemistry of both a lignite and pyrite containing spoil as well as a lignite and pyrite free spoil. The lignite and pyrite containing spoil was ameliorated with fly ash from a lignite power plant (17–21 t ha−1 CaO), whereas the lignite and pyrite free site received 7.5 t ha−1 CaO in form of limestone. Fertilizer application rates were: mineral fertilizer 120 N, 100 P and 80 K kg ha−1. 19 t ha−1 sewage sludge and 22 t ha−1 compost were applied. Soil solution was sampled in 20, 60 and 130 cm depth for the period of 16 months. Solution was collected every fortnight and analysed for pH, EC, Ca2+, Mg2+, K+, Na+, Fen+, Aln+, Mn2+, Zn2+, NO3 −, NH4 +, SO4 2−, Cl−, PO4 3−, Cinorg and DOC. Lignite and pyrite containing spoil differed clearly from lignite and pyrite free spoil regarding soil solution concentrations and composition. Acidity (H+) produced by pyrite oxidation led to an enhanced weathering of minerals and, therefore, to at least 10 fold higher soil solution concentrations compared to the lignite and pyrite free site. Major ions in solution of the lignite and pyrite containing site were Ca2+, Mg2+, Fen+, Aln+ and SO4 2−, whereas soil solution at the lignite and pyrite free site was dominated by Ca2+, Mg2+ and SO4 2−. At both sites application of mineral fertilizer led to an immediate but short term (about 1 month) increase of NO3 −, NH4 + and K+ concentrations in soil solution down to a depth of 130 cm. Application of sewage sludge caused a long term (about 16 months) increase of NO3 3 − in the topsoil, whereas NO3 − concentrations in the subsoil were significantly lower compared to the mineral fertilizer plot. Compost application resulted in a strong long-term increase of K+ in soil solution, whereas NO3 − concentrations did not increase. Concentrations of PO4 3− in soil solution depend on solution pH and were not correlated with any treatment.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1004421501867
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  • 2
    Electronic Resource
    Electronic Resource
    Organic matter composition and degree of humification in lignite-rich mine soils under a chronosequence of pine (1999)
    Springer
    Plant and soil 213 (1999), S. 161-168 
    Details
    ISSN: 1573-5036
    Keywords: 14C activity ; 13C CPMAS NMR spectroscopy ; lignite ; mine soils ; soil organic matter ; wet chemical analyses
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In the Lusatian mining district, in the eastern part of the Federal Republic of Germany, organic matter of reclaimed mine soils consists of a mixture of lignite and recently formed soil organic matter (recent carbon). The aim of the study was to investigate the recent carbon accumulation and the degree of humification of a chronosequence of young mine soils under forest. The lignite content of the forest floor, Ai (0–5 cm) and Cv horizons (1 m depth) was determined by 14CU activity measurements and the structural composition of the organic matter was characterised by 13C CPMAS NMR spectroscopy. To obtain a characterisation of the degree of humification, the soil samples were analysed for the content of polysaccharides, proteins, lignin and lipids by wet chemical methods. 14C activity measurements indicate that at the oldest site, comparable amounts of carbon accumulated in the first few centimetres of the soil profile than in natural forest soils. 13C CPMAS NMR spectra of the organic matter in the Ai horizons of the three soil profiles were dominated by aromatic and alkyl carbon species characteristic for lignite, but indicated as well an increasing contribution of carbon species from decomposing plant litter with soil age. When the results from wet chemical analyses were normalised to the total carbon content no changes with age could be noticed. After normalisation of the amount of litter compounds to the recent carbon content, the carbon identified by plant litter compound analysis decreased with increasing depth and increasing age of the soils. After 32 years the values are comparable to those of natural forest soils. These observations were confirmed by increasing degree of lignin alteration with stand age and soil depth. The data of wet chemical analyses complement data obtained by 14C activity measurements and 13C CPMAS NMR spectroscopy and lead to the conclusion that 32 years after reforestation the degree of humification of the soil organic matter is in the same range as those of natural sites.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1004454826537
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    Paper (German National Licenses)
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