ISSN:
0044-2313
Keywords:
Nickel(0) complexes
;
isocyanide ligands
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Triphenylphosphane Nickel(0) Complexes with Isocyanide Ligands - [(RNC)nNi(PPh3)4-n] (n = 1-3)Synthesis and properties of the isocyanide triphenylphosphane nickel(0) complexes [(RNC)Ni(PPh3)3], [(RNC)2Ni(PPh3)2] and [(RNC)3Ni(PPh3)] (R = tBu, Cy, PhCH2, p-TosCH2) are described. I.r. and 31P n.m.r. spectra were recorded and the X-ray crystal structure of [(PhCH2NC)2Ni(PPh3)2] was determined.
Notes:
Synthese und Eigenschaften von Isocyanid-Triphenylphosphan-Nickel(0)-Komplexen der Typen [(RNC)Ni(PPh3)3], [(RNC)2Ni(PPh3)2] und [(RNC)3Ni(PPh3)] (R = tBu, Cy, PhCH2, p-TosCH2) werden beschrieben.Die Charakterisierung der genannten Komplexe erfolgte mit Hilfe der IR- und 31P-NMR-Spektroskopie, von [(PhCH2NC)2Ni(PPh3)2] wurde die Molekülstruktur bestimmt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19946201206
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