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  • Analytical Chemistry and Spectroscopy  (1)
  • chromosomal localization  (1)
  • interstitial carbido ligand  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Synthesis and structural characterization of the hydrido carbido ruthenium cluster [PPh4][Ru6C(CO)16H] (1992)
    Springer
    Journal of cluster science 3 (1992), S. 489-497 
    Details
    ISSN: 1572-8862
    Keywords: Hydrido cluster ; ruthenium cluster ; interstitial carbido ligand ; crystallographic structure ; monoanionic cluster
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract According to the protonation of [PPh4]2[Ru6C(CO)16] (1b) withp-toluene-sulfonic acid, a hydrido ruthenium cluster [PPh4][Ru6C(CO)16H] (3b) was obtained in 53% yield, which readily decomposed in protic solvents even at −20°C to yield1b, Ru6C(CO)16H2, and Ru5C(CO)15. Cluster3b was characterized by single-crystal X-ray analysis. The six metal atoms are arranged in the form of an octahedron with the carbido ligand located in the center. There are 13 terminal carbonyl, three bridging carbonyl, and a bridging hydrido ligands.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00702754
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  • 2
    Electronic Resource
    Electronic Resource
    Fluorescencein situ hybridization analysis of chromosomal localization of three human cytochrome P450 2C genes (CYP2C8, 2C9, and 2C10) at 10q24.1 (1994)
    Springer
    Journal of human genetics 39 (1994), S. 337-343 
    Details
    ISSN: 1435-232X
    Keywords: fluorescencein situ hybridization ; CYP2C subfamily ; chromosome 10 ; chromosomal localization ; polymerase chain reaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Chromosomal localization of three human cytochrome P450 genes belonging to the CYP2C subfamily (CYP2C8, 2C9, and 2C10) was identified by fluorescencein situ hybridization (FISH). An original MP-8 clone was used as a DNA probe for the assignment of the CYP2C10 gene, while two cDNA probes, a 1.37 kb fragment of CYP2C8 and a 1.19 kb fragment (MP-20 and MP-4 clones, respectively) by polymerase chain reaction using a single human liver cDNA library. The results showed that three human CYP2C8, 2C9, and 2C10 cDNAs were located at the same subchromosomal region, 10q24.1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01874052
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  • 3
    Electronic Resource
    Electronic Resource
    Mass spectra of π-cyclopentadienyl-diene cobalt complexes (1970)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1970), S. 23-29 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Many reports on the mass spectra of organotransition-metal complexes have appeared in recent years,1 whilst there have only been a few reports on the mass spectra of transition metal olefin complexes, some metal carbonyl olefin complexes234 and π-cyclooctenyl-π-cyclooctadienyl cobalt.5 Recently fragmentation paths of π-cyclopentadienyl-cyclooctadiene rhodium were elucidated by King.6 The present authors found metastable ions in the mass spectra of π-cyclopentadienyl-diene cobalt complexes as well as in the mass spectra of π-cyclopentadienyl-diene rhodium complexes.7.In the present paper the authors wish to report the mass spectra of several π-cyclopentadienyl diene cobalt complexes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210030104
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