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Hydrolysis of N-methyl-N-nitroso-p-toluenesulphonamide in micellar media (1998)

García-Río, L. ; Hervés, P. ; Leis, J. R. ; [et al.]

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 584-588

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ISSN: 0894-3230

Keywords: N-methyl-N-nitroso-p-toluenesulphonamide ; hydrolysis ; micellar media ; pseudophase model ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The acid and basic hydrolysis of N-methyl-N-nitroso-p-toluenesulphonamide (MNTS) was studied in different micellar aggregates (CTACl, CTABr, TTABr, LTABr, and OTACl). The effect of mixed micelles (OTAX-LTAX) was also studied. The kinetic behaviour was explained on the basis of the pseudophase model, from which the binding constants of MNTS to different micelles, the ion exchange constants and the reactivity constants in the micellar pseudophase were obtained. © 1998 John Wiley & Sons, Ltd.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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