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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 11 (1990), S. 477-486 
    ISSN: 1572-9567
    Keywords: density ; equation of state ; high pressure ; Tait equation ; tetraethylsilane ; tetraethoxysilane ; tetramethylsilane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Accurate density data for tetramethylsilane, tetraethylsilane, and tetraethoxysilane in the temperature range from 283.15 to 333.15 K under pressure up to 100 MPa have been measured in order to test existing correlation methods. We have also measured the saturated liquid densities of tetramethylsilane, tetraethylsilane, and tetraethoxysilane in the temperature range from 283 to 343 K. The modified Rackett equation and the COSTAD correlation were used to correlate the saturated liquid density data. The Tait equation and a modified van der Waals equation of state were used to correlate the liquid density data under pressure. It was found that the average absolute deviations of the experimental values from those calculated with the Tait equation and the modified van der Waals equation of state were less than 0.01 and 0.21%, respectively. The effective hard sphere diameters for these three silane compounds were determined from the modified van der Waals equation of state parameter. It was found that the effective hard-sphere diameter decreases with temperature.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9567
    Keywords: bellows piezometer ; density ; high pressure ; poly(dimethylsiloxane) ; sing-around technique ; ultrasonic speed
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The ultrasonic speeds and densities of poly(dimethylsiloxane), viscosity grades 30 and 50×10−4 m · s−1 at 298.15 K, were measured at 298.15, 303.15, and 308.15 K. The measurements were carried out using new apparatuses, one for measurement of the speed under pressures up to 200 MPa and another for measurement of the density under pressures up to 100 MPa. The former is constructed with a sing-around technique of the fixed-path type operated at a frequency of 2 MHz, and the latter is a dynamic bellows piezometer. The probable uncertainty in the present results is within ±0.23% for speed and ±0.19% for density for all the experimental conditions. The ultrasonic speed in these fluids at first increases rapidly with pressure and then indicates a mild rise in the highpressure region. Similar pressure effects are observed for the density. The relationship between the speed and the density satisfied a first-order function well. The isentropic compressibility, derived from the speed and density, also showed a large pressure effect. The values and its pressure effects seemed almost independent of the viscosity of poly(dimethylsiloxane).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 10 (1989), S. 661-671 
    ISSN: 1572-9567
    Keywords: binary mixture ; critical region ; high pressure ; R22 ; R502 ; R115 ; refrigerants ; ultrasonics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The ultrasonic speed u of [(1 -ϰ) CHClF2(1) + ϰC2ClF5(1)] including the azeotropic mixture [CHClF2(1) + C2ClF5(1)] was measured at pressures up to 51 MPa within the temperature range 283.15 to 373.15 K, using a sing-around technique operated at a frequency of 2 MHz with an estimated uncertainty of less that ±2.4 m·s−1. For ϰ = 0.1537 and 0.6268, measurements of the vapor pressure are also reported.
    Type of Medium: Electronic Resource
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