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Si6H6 revisited: The hexasilaprismane-to-hexasilabenzene and hexasila-dewarbenzene interconversion (1995)

Janoschek, R.

Springer

Journal of inorganic and organometallic polymers and materials 5 (1995), S. 155-161

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ISSN: 1572-8870

Keywords: Hexasilabenzene ; hexasilaprismane ; hexasila Dewarbenzene ; interconversion ; kinetic instability ; photochemistry

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Ab initio calculations on the parent hexasilaprismane (2) and its less stable valence isomers hexasilabenzene (1) and hexasila Dewarbenzene (3) have been performed. Calculated transition structures for the interconversion of the isomers indicate kinetic instability of the isomers1 and3.Ab initio (Cl(S) calculations on the S1 photochemistry of the isomers explain the features of the recently observed UV spectra.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01058143

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