ISSN:
1588-2837
Keywords:
NO decomposition
;
hexagonal perovskites
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The catalytic activity of Ba2Ru0.67Bi1.33O6, Ba2RuBiO6, Ba3Ru2BiO9 and BaRuO3 towards NO-decomposition prior to and after treatment with NH3 has been studied. About 100% degree of conversion has been achieved at 400°C for samples with the highest percentage of hexagonal stacking in their crystal structures. It has been shown that the active sites are units of two or three face-sharing [RuO6] octahedra in which a strong Ru−Ru interaction takes placevia the common faces.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02475440
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