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  • 1
    ISSN: 1573-1561
    Keywords: Heliothis zea ; corn earworm moth ; insect pheromones ; glass open-tubular capillary chromatography ; gas chromatography-mass spectrometry ; (Z)-1 1-hexadecenal ; (Z)-9-hexadecenal ; (Z)-7-hexadecenal ; hexadecanal ; insect behavior
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Glass open-tubular capillary Chromatographic and combined glass open-tubular capillary chromatographic-mass spectrometric analyses of ovipositor washes of femaleHeliothis zea, chemical characterization, chemical synthesis, and laboratory and field bioassays showed that the ovipositor wash of the species is made up of 90–95% (Z)-11-hexadecenal, 1–2% (Z)-9-hexadecenal, 0.4–2% (Z)-7-hexadecenal, and 2–7% hexadecanal. Stimuli containing a binary mixture of (Z)-11-hexadecenal and (Z)-9-hexadecenal or the binary mixture in combination with any of the other aldehydes identified from the females elicited intense attraction and close-range precopulatory reactions fromH. zea males.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: Heliothis virescens ; tobacco budworm ; sex pheromones ; reproductive isolation ; gas open tubular capillary chromatography ; mass spectrometry ; insect behavior ; (Z)-11-hexadecenal ; (Z)-9-hexadecenal ; (Z)-7-hexadecenal ; (Z)-9-tetradecenal ; (Z)-11-hexadecen-1-ol ; tetradecanal ; hexadecanal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract (Z)-11 -Hexadecenal (77–91%), (Z)-7-hexadecenal (0.1–2%), (Z)-9-hexadecenal (0.3–2%), hexadecanal (3–19%), (Z)-11-hexadecen-1-ol (1–5%), tetradecanal (1–3%), and (Z)-9-tetradecenal (1–3%) were identified from the heptane washes of the ovipositor of femaleHeliothis virescens (F.) females. In field bioassays, a 152-μg mixture of these seven compounds deployed in an insect trap exceeded the attractiveness of 4 virgin femaleH. virescens for males and was 5–6 times more attractive than a mixture of (Z)-1 1-hexadecenal and (Z)-9-tetradecenal (virelure) that was previously reported as the sex pheromone of the species. Four of the seven compounds produced byH. virescens females are also produced byH. zea (Boddie). Specificity of pheromonal signals among the two species is ostensibly dependent upon one or more of the three additional compounds [tetradecanal, (Z)-9-tetradecenal, and (Z)-1 1-hexadecen-1-ol] produced by femaleH. virescens.
    Type of Medium: Electronic Resource
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