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Excess Thermal Expansion Factors of Polar Mixtures and Aqueous Solutions (1999)

Tamura, K.

Springer

Journal of thermal analysis and calorimetry 57 (1999), S. 759-763

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ISSN: 1572-8943

Keywords: aqueous solution ; excess thermal expansion factor ; polar mixture ; the cross entropyvolume fluctuation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Excess thermal expansion factor of non-polar mixtures is the order of 10−6 K−1 and within an experimental error. On the other hand, those of polar mixtures and aqueous solutions are very large and the order of 10–5 K−1, up to the order of 10−4 K−1 in an extreme case. The excess thermal expansion factors express well the excesses of entropy volume cross fluctuation and enthalpy volume cross fluctuation estimated from thermal expansion factor and molar volume. Those of aqueous solutions are, however, reduced by small molar volume of water.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010173604826

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