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Kinetic coupling in and between catalytic cycles (1994)

Boudart, M. ; Djéga-Mariadassou, G.

Springer

Catalysis letters 29 (1994), S. 7-13

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ISSN: 1572-879X

Keywords: kinetic coupling ; equilibrated steps ; one-way steps ; asymmetric hydrogenation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Quasi-equilibrium between catalytic reactive intermediates and reactant or product molecules is a common assumption. As process conditions vary, this assumption may cease to be valid because of kinetic coupling between steps in the catalytic cycle. In the case of coupled catalytic cycles, kinetic coupling manifests itself by substantial changes in selectivity. An elegant example of catalytic coupling in and between catalytic cycles is the change in enantioselection with H2 pressure for the asymmetric hydrogenation of a prochiral alkene, as discovered in the Halpern laboratory.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00814246

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