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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 665-672 
    ISSN: 0887-624X
    Keywords: cationic polymerization ; epoxide network ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The theory of network formation developed for the cationic polymerization of diglycidyl ether of Bisphenol A was modified for the presence of a reactive diluent γ-butyrolactone and tested by comparison with experimental results. It was shown that the theory predicts quite reasonably the structure evolution during polymerization characterized by growth of the polymer fraction, gelation, increase in gel fraction, as well as the equilibrium rubber modulus of cured samples. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 665-672, 1997
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 35 (1997), S. 651-663 
    ISSN: 0887-624X
    Keywords: cationic polymerization ; epoxide network ; theory of network formation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Network formation in cationic polymerization of polyepoxides was treated using a combination of kinetic theory and the statistical theory of branching processes (TBP). The complex reaction mechanism involved a degradative termination reaction affecting the molecular weight distribution of the primary chains. Moreover, formation of low-molecular-weight products, initiation, two mechanisms of propagation and transfer were taken into account. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 651-663, 1997
    Type of Medium: Electronic Resource
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