ISSN:
1573-9171
Keywords:
carbonylation
;
dicobalt octacarbonyl
;
benzenesulfonyloxyacetonitrile
;
ethyl ester of the mononitrile of malonic acid
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A new method has been developed for the synthesis of the ethyl ester of the mononitrile of malonic acid by the carbonylation of benzenesulfonyloxyacetonitrile in absolute ethanol in the presence of cobalt carbonyl. The yield of the desired product was 30% with 60–90% conversion of the starting compound. The effects of temperature, pressure, and reaction time were studied.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00863942
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