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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Microchimica acta 101 (1990), S. 173-188 
    ISSN: 1436-5073
    Keywords: ceramics ; atomic spectrometry ; inorganic analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The analytical characterization required in the development and in the quality control of new ceramics is discussed. For the basic substances, the problems encountered in the development of routine techniques for a direct and reliable analysis of Al2O3, AlN, Si3N4, SiC, and ZrO2 powders are reported. Among the atomic spectrometric methods, especially slurry atomization ICP-spectrometry is described. Also the problems encountered in the development of combined procedures as required for the characterization of reference samples are presented. Methods for the direct bulk analysis of ceramics and microdistributional analysis, as they are now under development with laser-based techniques and various probe techniques, are described as well.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1436-5073
    Keywords: decomposition ; mass spectrometry ; ceramics ; fluorine ; isotope ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The features of a combustion with elementary fluorine for the case of compact SiC ceramics and model substances for boron containing ceramics (H3BO3 and Na2B4O7) were investigated with the aim of their decomposition and analysis. On-line detection of the gaseous decomposition products by quadrupole mass spectrometry using electron impact ionisation was studied. Limitations by blanks and transport interferences were investigated. Standard addition as well as the isotope dilution technique were used for calibration in the case of B, C and W at the trace and major component level.
    Type of Medium: Electronic Resource
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