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  • 2-(dimethylaminomethyl)ferrocenyl compounds  (3)
  • ddc:330
  • C72
  • 1
    Electronic Resource
    Electronic Resource
    Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. 58. Zur Kenntnis von 2-(Dimethylaminomethyl)ferrocenyl-Verbindungen des Vanadiums, Molybdäns, Wolframs, Thoriums und Urans (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 613 (1992), S. 88-92 
    Details
    ISSN: 0044-2313
    Keywords: Transition metal alkyl compounds ; vanadium ; molybdenum ; tungsten ; thorium ; uranium ; 2-(dimethylaminomethyl)ferrocenyl compounds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Transition Metal Alkyl Compounds. 58 On 2-(Dimethylaminomethyl)ferrocenyl Compounds of Vanadium, Molybdenum, Tungsten, Thorium, and UraniumEarlier results according to which dimethylaminomethylferrocenyl groups (FcN) are able to form stable organometallic chelate compounds were confirmed by synthesis of the heterobimetallic chelate compounds (FcN)2VO · Li(acac) II, (FcN)MoO2(acac) III, (FcN)WOCl3 IV, (FcN)Th(acac)3 V, and (FcN)UO2(acac) VI from the corresponding metal acetylacetonates or oxidchlorides and (FcN)Li I. The new compounds were characterized by elemental analysis, the i.r., 1H-n.m.r., and electron spectra and by their effective magnetic moments.
    Notes: Frühere Befunde, wonach Dimethylaminomethylferrocenyl-Gruppen (FcN) zur Bildung stabiler Organoübergangsmetallchelate befähigt sind, wurden durch die Synthese der heterobimetallischen Chelatkomplexe (FcN)2VO · Li(acac) II, (FcN)MoO2(acac) III, (FcN)WOCl3 IV, (FcN)Th(acac)3 V und (FcN)UO2(acac) VI aus den betreffenden Metalloxidchloriden bzw. -acteylacetonaten und (FcN)Li I bestätigt.  -  Die erhaltenen Verbindungen wurden durch Elementaranalysen, IR-, 1H-NMR- und UV-VIS-Spektren sowie Bestimmung der effektiven magnetischen Momente charakterisiert.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926130115
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  • 2
    Electronic Resource
    Electronic Resource
    Beiträge zur Lanthanoidchemie. II. Zur Kenntnis von 2-(Dimethylaminomethyl)ferrocenyl-Verbindungen des Yttriums, Dysprosiums und Holmiums (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 618 (1992), S. 163-167 
    Details
    ISSN: 0044-2313
    Keywords: Organolanthanide chemistry ; yttrium ; dysprosium ; holmium ; 2-(dimethylaminomethyl)ferrocenyl compounds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to Organolanthanide Chemistry. II. On 2-(dimethylaminomethyl)ferrocenyl Compounds of Yttrium, Dysprosium, and HolmiumEarly reports about the ability of the 2-(dimethylaminomethy1)ferrocenyl group to form stable heterobimetallic organolanthanide(III) compounds have been confirmed by the synthesis of the organolanthanide(III) derivatives (C5H5)2Ln(FcN) [Ln = Y (II), Dy (III), Ho (IV)], C5H5Dy(FcN)2 · 2,5 THF (V) und C5H5Ln(FcN)Cl [Ln = Dy (VI), Ho (VII)] from the corresponding cyclopentadienyllanthanide(III) chlorides (C5H5)2LnCl or C5H5LnCl2 resp. and (FcN)Li (I). The products have been characterized by elemental analyses, IR-, 1H-NMR, 13C-NMR and UV/Vis spectra as well as mass spectra and the determination of their effective magnetic moments.
    Notes: Frühere Befunde, wonach 2-(Dimethylaminomethyl)ferrocenyl-Gruppen (FcN) zur Bildung stabiler, heterobimetallischer Organolanthanoid(III)-Verbindungen befähigt sind, wurden durch die Synthese der Organoseltenerd(III)-Derivate (C5H5)2SE(FcN) [SE = Y (II), Dy (III), Ho (IV)], C5H5Dy(FcN)2 · 2,5 THF (V) und C5H5SE(FcN)Cl [SE = Dy (VI), Ho (VII)] aus den betreffenden Cyclopentadienylseltenerd(III)-chloriden (C5H5)2SECl bzw. C5H5SECl2 und (FcN)Li (I) bestätigt. Die erhaltenen Verbindungen wurden durch Elementaranalysen, IR-, 1H-NMR-, 13C-NMR- und UV-Vis-Spektren sowie durch Bestimmung der effektiven magnetischen Momente und die Aufnahme von Massenspektren charakterisiert.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926180128
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  • 3
    Electronic Resource
    Electronic Resource
    Beiträge zur Lanthanoidchemie. III Zur Kenntnis von 2-(Dimethylaminomethyl)ferrocenyl-Verbindungen des Samariums und Yttriums (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1957-1961 
    Details
    ISSN: 0044-2313
    Keywords: Organolanthanide chemistry, samarium, yttrium ; 2-(dimethylaminomethyl)ferrocenyl compounds ; heterobimetallic organolanthanide chelate complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contribution to Organolanthanoide Chemistry. III. On 2-(Dimethylaminomethyl)ferrocenyl Compounds of Samarium and YttriumEarlier results, indicating the ability of the bulky 2-(dimethylaminomethyl)ferrocenyl-group (FcN) to form thermocally stable, heterobimetallic organolanthanide compounds, were proved by the synthesis of organo-rare-earth derivatives (C5Me5)2Sm(FcN) (II), (C5H5)Sm(FcN)Cl (III), respectively (C5Me5)Y(FcN)Cl (IV) from the corresponding complex cyclopentadienyl rare-earth chlorides (C5Me5)2SmCl · KCl · THF, (C5H5)SmCl2 · THF and (C5Me5)YCl2 · KCl · 1,8 THF and 2-(dimethylaminomethyl)ferrocenyl lithium (FcN)Li (I) as organylating agent. The synthesized compounds were proved by elementary analysis, IR, 1H, 13C NMR and UV-VIS spectra as well as by measuring the magnetic moments and by mass spectroscopy.
    Notes: Frühere Befunde, wonach die voluminöse 2-(Dimethylaminomethyl)ferrocenyl-Gruppierung (FcN) zur Bildung thermisch stabiler, heterobimetallischer Organolanthanoid(III)-Verbindungen befähigt ist, wurden durch die Darstellung der Organoseltenerd(III)-Derivate (C5Me5)2Sm(FcN) (II), (C5H5)Sm(FcN)Cl (III) und (C5Me5)Y(FcN)Cl (IV) aus den betreffenden komplexen Cyclopentadienyl-Seltenerd(III)-chloriden (C5Me5)2SmCl · KCl · THF, (C5H5)SmCl2 · THF bzw. (C5Me5)YCl2 · KCl · 1,8 THF und 2-(Dimethylaminomethyl)ferrocenyl-Lithium (FcN)Li (I) als Organylierungsmittel bestätigt. Die erhaltenen Verbindungen wurden durch Elementaranalysen, IR-, 1H-NMR-, 13C-NMR- und UV-VIS-Spektren sowie durch die Ermittlung der effektiven magnetischen Momente und die Aufnahme der Massenspektren charakterisiert.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936191122
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