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  • 1
    ISSN: 1573-0867
    Keywords: crop response ; leaching ; liming ; nonexchangeable potassium ; nutrient retention
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime and leaching on dry matter production and nutrient uptake by maize (Zea mays) were studied in 21 cm deep leaching columns/pots filled with an Oxic Inceptisol (12 kg) from Alafua, Western Samoa. Ground (〈0.25mm) coralline material containing approximately 80% CaCO3 was used as lime. There were 12 treatments, factorially arranged: 4 liming rates (0, 10.5, 21.0 and 31.5 g pot−1) which were applied to the top 5 cm of the pots, and 3 K applications (0, 0.69 1.38 g pot−1) which were applied after the initial leaching period of 10 days (3 1 pot−1 day−1) following the lime applications. Leaching continued for 15 more days, using 1 1 pot−1 day−1, after K fertilizations. During the initial leaching period, liming intensified K losses. The applied Ca-ions displaced the exchangeable K which was subsequently leached out of the pots. During the second leaching period, liming increased K retention only when K concentrations in the soil were high (treatment receiving 1.38 g K pot−1). These effects of liming and leaching on K retention were not detectable in the nutrient uptake of maize grown for 50 days after the second leaching period. This may have been because the leaching losses made up only approximately 2 % of the K-turnover in the pots. A calculated nutrient balance for the pots showed that a large portion of K taken up by maize came out of a pool of nonexchangeable K. The Alafua soil had 0.45 % (11.5 cmol(+)kg−1) total-K, indicating a relatively large K reserve. Since mineralogical studies failed to detect the presence of any known 2:1 minerals, the K reserve of the Alafua soil might be located in amorphous material.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5036
    Keywords: Ca deficiency ; critical Ca level ; crop response ; liming ; Mn toxicity nutrient interaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime, in combination with 3 kg Cu ha−1 plus 3 kg Zn ha−1, on yield and nutrient uptake by peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0–10 mm) coralline lime material containing 31.1% Ca and 1.7% Mg was used as lime at 0, 555, 2222 and 5000 kg ha−1. In the Togitogiga soil, which had the lowest level of exchangeable Ca, peanut yield increased by 6 fold after liming with 555 kg ha−1, relative to the unamended control. This yield increase was associated with reduced Mn toxicity as well as reduced Ca deficiency. The alleviation of Mn toxicity was not likely due to decreased Mn solubility because the lime application (555 kg ha−1) increased soil pH by 〈0.1 unit. Rather it was the increased Ca availability which reduced the Mn toxicity through a Ca/Mn antagonism. The critical range of exchangeable Ca for peanut growth was found to be about 1.5–1.6 cmol 1/2Ca2+ kg−1. A Ca/Mn-ratio 〉80 was required for a desirable Ca/Mn balance in peanut tissue. On the other two locations (with exchangeable Ca levels of 1.5–1.6 cmol 1/2Ca2+ kg−1), liming increased peanut yields by 15–20%. Additions of Cu plus Zn also increased the yields, although the increases were small (7%) and not significant at the 95% probability level.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 36 (1993), S. 211-219 
    ISSN: 1573-0867
    Keywords: banding ; broadcasting ; Ca deficiency ; crop response ; liming ; Mn toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime on yield and nutrient uptake by sweet corn (Zea mays saccharata Sturt.) and peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0-10 mm) coralline material containing 31.1% Ca and 1.67% Mg was used as lime. There were two modes of application: band and broadcast, and three rates: 6, 12 and 18 ton ha−1. In the highest rainfall location, marketable yields were increased by 250% for peanut and 160% for sweet corn by liming at 6 ton ha−1, relative to the unamended control. Peanut yield increases were associated with reduced Mn toxicity and/or with Ca and Mg deficiency. Sweet corn was less susceptible to Mn toxicity, but more responsive to exchangeable Ca. The critical level of exchangeable Ca was found to be about 2.0 cmol(+)kg−1. Applying lime to a band of 0.25-m wide did not reduce yield relative to broadcast. Soil cultivation caused the lime to spread over a wider band, diluting the applied calcium with a larger soil volume, suggesting that less than 6 ton ha−1 broadcast coarse coralline lime could still be adequate for most Samoan soils.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 18 (1997), S. 1930-1942 
    ISSN: 0192-8651
    Keywords: molecular simulation ; periodic boundary conditions ; box shape ; lattice ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: In molecular simulations with periodic boundary conditions the computational box may have five different shapes: triclinic; the hexagonal prism; two types of dodecahedrons; and the truncated octahedron. In this article, we show that every molecular simulation, formulated in one of these boxes, can be transformed into a simulation in one of the other ones. The transformation can be done in a preprocessing phase. The simulation in the new box is exactly identical to the simulation in the original one. This means that every molecular simulation may be done in the same type of box. Because the triclinic box is the easiest one to implement, we pay special attention to how to transform the other four box types into triclinic boxes. As a consequence, simulations in the often used truncated octahedron are superfluous; they may be done in a much simpler way in a triclinic box.   © 1997 John Wiley & Sons, Inc.   J Comput Chem 18: 1930-1942, 1997
    Additional Material: 15 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 18 (1997), S. 1463-1472 
    ISSN: 0192-8651
    Keywords: constraints ; molecular dynamics ; Langevin dynamics ; SHAKE ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: In this article, we present a new LINear Constraint Solver (LINCS) for molecular simulations with bond constraints. The algorithm is inherently stable, as the constraints themselves are reset instead of derivatives of the constraints, thereby eliminating drift. Although the derivation of the algorithm is presented in terms of matrices, no matrix matrix multiplications are needed and only the nonzero matrix elements have to be stored, making the method useful for very large molecules. At the same accuracy, the LINCS algorithm is three to four times faster than the SHAKE algorithm. Parallelization of the algorithm is straightforward.   © 1997 John Wiley & Sons, Inc.   J Comput Chem 18: 1463-1472, 1997
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 14 (1980), S. 337-343 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Paramagnetic NMR shift reagents, Eu(fod)3 and Pr(fod)3, have been applied to study the one-ene conformations of isomeric dienones. The results obtained using various complex formation models are analysed. The preferred model suggests participation of both carbonyl oxygen Ione pairs in binding with the shift reagents. Criteria for the estimation of errors in the determination of the structure parameters of the substrate-paramagnetic reagent complexes are suggested. The data obtained using NMR shift reagents are consistent with the existence of dienone α,β-cis-isomers as s-cis-conformers only, with the carbonyl group lying out of the plane of all the other atoms of the molecule. Both s-cis and s-trans conformers occur in dienone α,β-trans-isomers.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The activation energy parameters for the reaction of PdX42- (X=Cl-, Br-) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each case simplifies to kobs=k[L] where L=tu or seu, and only ligand-dependent rate constants are observed at 25°C. The ligand-dependent rate constants for the first identifiable step in the PdCl42- + X system is (9.1±0.1) × 103 M-1 sec-1 and (4.5±0.1) × 104 M-1 sec-1 for X=tu and seu, respectively, while for the PdBr42- + X system it is (2.0±0.1) × 104 M-1 sec-1 and (9.0±0.1) × 104 M-1 sec-1 for X=tu and seu, respectively.
    Additional Material: 4 Tab.
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