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  • Chemistry  (5)
  • Polymer and Materials Science  (2)
  • conductance  (1)
  • enthalpy  (1)
  • 5'-O-demethyl-8-O-methyl-dioncophylline A
  • 1985-1989  (3)
  • 1970-1974  (4)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 16 (1987), S. 985-997 
    ISSN: 1572-8927
    Schlagwort(e): Aqueous solution ; cell constant ; conductance ; electrolytic conductivity ; potassium chloride ; primary ; resistance ; resistivity, secondary, standards, and temperature scale
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Measurements of aqueous electrolytic conductance are performed routinely in a variety of disciplines and industries. Conductivity is a measure of the ionic content in solution and thus has applications in pharmaceuticals, power plants, rainwater, lake surveys, and oceanography, to name a few. A thorough review of the measurement of and standards for aqueous electrolytic conductance is herein presented. At present, the most precise and accurate standards have been set forth by the International Organization of Legal Metrology (OIML), and have been adopted by most other standards organizations. However, the uncertainty assigned to these standards, especially the secondary standards, is somewhat larger than would be expected from the physical aspects of the measurement. Several changes in the units and measurement scales, including temperature, volume, molar mass, resistance, and concentration obfuscate the accuracy of these standards. In addition to the review, research is proposed, using a conductance cell with variable length, to establish new standards for aqueous electrolytic conductance.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 15 (1986), S. 675-692 
    ISSN: 1572-8927
    Schlagwort(e): Deuterium chloride ; deuterium oxide ; electrochemical cell ; emf ; enthalpy ; entropy ; free energy ; heat capacity ; isotope effect ; standard potential ; thermodynamics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The themodynamic properties of solutions of deuterium chloride (DCl) in deuterium oxide (D2O) have been determined from emf measurements of the electrochemical cell without transference from 5 to 50°C, and from 0.002 to 1.0 mol-kg−1. The standard potential of the silver/silver chloride electrode relative to the platinum/deuterium electrode has been determined. An equation for the Gibbs energy as a function of temperature has been derived from which the enthalpy, entropy, and heat capacity have been computed. Equations for the activity coefficient and the osmotic coefficient of DCl in D2O have been developed. The excess Gibbs energy of the solution and the excess partial molar free energy as a function of temperature have been calculated, from which the other excess thermodynamic properties have been computed. The values for the heat capacity and the apparent molar heat capacity have been compared with calorimetric data in the literature. The relative partial molar enthalpy has been calculated. The solvent isotope effect on the excess thermodynamic functions is discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 12 (1985), S. 105-123 
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Certain polymerization reactions show the formation of medium molecular weights at the beginning of the reaction, although they can be considered to be polycondensations. The principle of equal reactivity of the end groups is not given in this case. Intermediates more reactive than the monomer are formed during the reaction. Poly(oxy-2,6-dimethyl-l,4-phenylene), poly(l,4-phenylene sulfide) and poly(l,4-phenylene) are examples of this type of reaction. The formation of radical ions in these reactions is discussed and they are compared to Bunnett's SRN1-reactions.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 2 (1971), S. 135-144 
    ISSN: 0933-5137
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Beschreibung / Inhaltsverzeichnis: Analytical Chemistry used for developing new materials. The development of new materials constantly confronts the analyst with difficult new problems. Of particular importance for this work would be all methods permitting to lay bare the phase interface and to study their structure and perturbations of this structure. The analyst has to solve these problems in close contact with the technologists specializing in this modern technique.
    Notizen: Die Entwicklung neuer Werkstoffe stellt den Analytiker vor immer neue diffizile Aufgaben. Insbesondere dürften alle Verfahren, mit denen es gelingt, Phasengrenzflächen freizulegen und ihren Aufbau sowie Störungen in diesem Aufbau zu studieren, für diese Aufgaben von großer Bedeutung sein. Der Analytiker muß diese Aufgaben in engster Fühlung mit den Technologen, die sich dieser modernen Entwicklung verschrieben haben, lösen.
    Zusätzliches Material: 17 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 53 (1970), S. 1704-1708 
    ISSN: 0018-019X
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Am Beispiel der Synthese von O,O-Diacetyl-L-cyclodopa-methylester (12) wird eine allgemein anwendbare Methode zur selektiven Acylierung der phenolischen Hydroxylgruppen oder des Indolin-Stickstoffs am Cyclodopa (8) beschrieben. Die Verwendung von L-DOPA (5) als Ausgangsmaterial für die Cyclisierung erlaubt die Darstellung grösserer Mengen solcher Derivate.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 53 (1970), S. 964-973 
    ISSN: 0018-019X
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In a search for a new and efficient synthesis of the compound 7, the cyclization of 5 (obtained by a Michael-reaction from 3 and 4) was studied. Treatment of 5 with strong acid furnished the known dienedione 8. Mild acidic conditions gave the bridged alcohol 9 and other, unidentified products, rather than the desired enone 6. Under basic conditions, 5 did not cyclize to 6, but underwent retro-Michael reaction. Attempts were then made to convert the dienedione 8 to the 14α-enone 19. However, both catalytic hydrogenation and lithium-ammonia reduction of 8 yielded mainly 14β-products. In some hydrogenation experiments, isomerization of the dienedione 8 to the phenols 13 (major) and 14 (minor) occurred. The stereochemistry of the new isomeric des-A-androst-9-en-5, 17-diones (16, 17 and 20) was determined by chemical and spectroscopic methods.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    ISSN: 0018-019X
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Aus den N-Acyl-3-(3,4-dihydroxyphenyl)-L-alaninen 1a, 1b und 1c entstehen bei der Oxydation unter anderm die L-3-Acylamino-6,7-dihydroxy-hydrocumarine 2a, 2b und 2c. Diese Reaktion stellt einen präparativ brauchbaren Weg zur Synthese von 3-(2,4,5-Tri-hydroxyphenyl)-L-alanin (6-Hydroxy-L-DOPA, 3) aus 3-(3,4-Dihydroxyphenyl)-L-alanin dar.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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