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  • carbohydrates  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Thermodynamic studies of dilute aqueous solutions of cyclic ethers and simple carbohydrates (1972)
    Springer
    Journal of solution chemistry 1 (1972), S. 3-16 
    Details
    ISSN: 1572-8927
    Keywords: Aqueous ; cyclic ethers ; carbohydrates ; inositols ; apparent molal volume ; apparent molal compressibility ; density
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Apparent molal volumes and compressibilities are reported for dilute aqueous solutions of cyclic ethers, simple carbohydrates, and related polyhydroxy compounds. The results for carbohydrates are considered in the light of two theoretical descriptions of such systems, i.e., the semiideal solution approach of Stokes and Robinson, and the McMillan-Mayer theory ty[e of approach as employed by Kozak, Knight, and Kauzmann. It is concluded that neither model is satisfactory, and that for these solutions a specific hydration model, described in more detail in another paper, is more satisfactory.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00648413
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  • 2
    Electronic Resource
    Electronic Resource
    Conformation and hydration of sugars and related compounds in dilute aqueous solution (1973)
    Springer
    Journal of solution chemistry 2 (1973), S. 99-118 
    Details
    ISSN: 1572-8927
    Keywords: Heats of solution ; heat capacity ; dipole moments ; static permittivity ; carbohydrates ; dielectric relaxation ; sugar conformation ; alcohols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The effect of hydroxyl substitution on the nature of the hydration of an alkane chain has been studied by calorimetric techniques. Static permittivities (ɛ0) of a range of monosaccharides and related compounds in aqueous solution have also been determined. The (ɛ0) data, suitably processed, have provided information about the solute dipole moments. In conjunction with earlier results from volumetric, compressibility, and relaxation studies, the specific hydration model is further developed and the relationships between solute molecular conformations and solute-water interactions are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00651968
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    Paper (German National Licenses)
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