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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of fracture 89 (1998), S. 245-268 
    ISSN: 1573-2673
    Keywords: Weibull stress ; cleavage fracture ; fracture mechanics ; finite element analysis.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The Weibull stress is widely used as a measure of the probability of cleavage failure. In this work analytical and semi-analytical expressions for the Weibull stress are developed in terms of the remote loading parameters, J or K, and material properties. Results are presented for sharp cracks and notches in elastic and elastic-plastic materials under plane stress and plane strain conditions. The proposed relations enable Weibull stress estimates to be obtained without the need for costly finite element analyses and provide insight into the use of the Weibull stress as a parameter for the prediction of cleavage failure of cracked bodies. The expressions have been verified using finite element techniques and good agreement has been found throughout. The results of the analyses have been used to interpret the mesh size dependence of Weibull stress values obtained from finite element calculations.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 55 (1999), S. 797-806 
    ISSN: 1572-8943
    Keywords: cadmium coordination ; crystal structure ; enthalpy of solution ; lattice energy ; lattice enthalpy ; NTO salt ; preparation ; standard enthalpy of dehydration ; standard enthalpy of formation ; thermal decomposition mechanism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract [Cd(NTO)4Cd(H2O)6]·4H2O was prepared by mixing the aqueous solution of 3-nitro-1,2,4-triazol-5-one and cadmium carbonate in excess. The single crystal structure was determined by a four-circle X-ray diffractometer. The crystal is monoclinic, space group C2/c with crystal parameters of a=2.1229(3) nm, b=0.6261(8) nm, c=2.1165(3) nm, β=90.602(7)°, V=2.977(6) nm3, Z=4, Dc=2.055 g·cm−3, μ=15.45 cm−1, F(000)=1824, λ(MoKα)=0.071073 nm. The final R is 0.0282. Based on the results of thermal analysis, the thermal decomposition mechanism of [Cd(NTO)4Cd(H2O)6]·4H2O was derived. From measurements of the enthalpy of solution of [Cd(NTO)4Cd(H2O)6]·4H2O in water at 298.15 K, the standard enthalpy of formation, lattice energy, lattice enthalpy and standard enthalpy of dehydration have been determined as -(1747.8±4.8), -2394, -2414 and 313.6 kJ mol−1 respectively.
    Type of Medium: Electronic Resource
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