ISSN:
1572-8862
Keywords:
Ruthenium
;
clusters
;
bridging ligands
;
quinolines
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The reactions of [Ru3(CO)10(μ-dppm)] 4 with quinolines afforded [Ru3 (μ-CO)(CO)7{μ3-η2-P(C6H5)CH2P(C6H5)2)}{μ-η2-C9H5(R)N}] (8, R = 4-Me; 9, R = H) as the major products along with small amounts of known compound [Ru3(CO)9{μ3-η3-P(C6H5)CH2P(C6H5)(C6H4)}] 5. The molecular structure of 8 has been determined by single crystal X-ray studies. The reaction of 5 with 4-methylquinoline in refluxing cyclohexane afforded 8 and two known dinuclear compounds, [Ru2(CO)6{μ-CH2P(C6H5)(C6H4)P(C6H5}] 10 and [Ru2(CO)6 {μ-(C6H4)P(C6H5)(CH2)P(C6H5}] 11, in 40, 12, and 10% yields, respectively. The compounds 10 and 11 are also formed from the thermolysis of 4 in addition to the major compound 5. The solid state structure of the previously reported [Ru3(CO)10(η-H){μ-η2-C9H6N}] 2a is also reported for comparison.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021994116953
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