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The study of benzimidazoles (1993)

Turchaninov, V. K. ; Motvienko, E. A. ; Larina, L. I. ; [et al.]

Springer

Russian chemical bulletin 42 (1993), S. 1683-1689

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ISSN: 1573-9171

Keywords: UV-spectra ; photoelectron spectra ; benzimidazoles

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The nature of the first two long-wave bands in the UV spectra of 2-substituted benzimidazoles has been analyzed on the basis of photoelectron spectra (PES). Three basic types of spectroscopic situations are typical of these compounds: 1) a change in the sequence of the occupied MO of the ground state does not influence the order of the excited energy levels; 2) when the π-levels are in the same order, inversion of the excited states occurs; 3) reversal of the occupied π-MO of the ground state causes the inversion of the excited states.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00697040

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