ISSN:
1435-1536
Schlagwort(e):
Freely jointed chain
;
stiff chain
;
two-state model
;
partition function
;
force-extension relation
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
Notizen:
Abstract The configurational properties of a molecular chain are investigated. The chain consists of rigid rod segments, which are consecutively correlated. This correlation is described by a two-state model. In the first state, neighboring segments are freely hinged togethers whereas in the second state they are parallel. The partition function and the force-extension relation are calculated. They show significant differences as compared to the usual results for a freely jointed chain. Thus the experimentally observed force-extension relation of polymeric networks buil up of such chains might be affected.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00655671
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