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Zintl Phases: Transitions between Metallic and Ionic Bonding (1973)

Schäfer, Herbert ; Eisenmann, Brigitte ; Müller, Wiking

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 12 (1973), S. 694-712

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ISSN: 0570-0833

Keywords: Zintl phases ; Bond theory ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Experimental studies on compounds of alkali and alkaline earth metals with semi- and metametals have considerably broadened the basis for a discussion of the transition from metallic to ionic bonding. Current interest is focused mainly upon the elucidation of the principles governing the structure of such compounds which are subject to a wide range of variation within this class of materials. A new definition of the term Zintl phase is proposed after consideration of available findings.

Additional Material: 20 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.197306941

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