ISSN:
1573-1111
Keywords:
Nitrobenzo-15-crown-5
;
dinitrobenzo-15-crown-5
;
dinitrodibenzo-18-crown-6 acetonitrile solvate
;
X-ray crystal structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The crystal structures of three nitrated benzocrown ethers have been determined. Nitrobenzo-15-crown-5 crystallizes in the orthorhombic space group,Pca21, witha = 15.367(2),b = 4.8499(8),c = 19.963(5)Å, andD calc = 1.40 g cm−3 forZ = 4. Dinitrobenzo-15-crown-5 crystallizes in the monoclinic space group,P21/n, witha = 11.716(2),b = 8.495(3),c = 17.441(5)Å,β = 108.40(2)° andD calc = 1.44 g cm−3 forZ = 4.Dinitrodibenzo-18-crown-6·2CH3CN ismonoclinic,P21/n,witha = 8.138(2),b = 20.435(9),c = 15.953(9)Å,β = 100.55(4)° andD calc = 1.36 g cm−3 forZ = 4. The nitro substituents are in the plane of the benzo ring except in the sterically congested dinitrobenzo-15crown-5. The observed crown ether conformations are similar to their substituted analogs.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01042780
Permalink