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    Electronic Resource
    Electronic Resource
    Reactivity of tungsten carbides I. Catalytic and temperature-programmed reactions of methanol (1991)
    Springer
    Catalysis letters 8 (1991), S. 107-114 
    Details
    ISSN: 1572-879X
    Keywords: Tungsten carbide ; methanol reactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract When methanol reacts over tungsten carbide in a steady-state catalytic mode, methyl formate is formed with a selectivity higher than 90%. On the other hand, temperature-programmed decomposition of methanol preadsorbed on the same surface produces mostly carbon monoxide. The difference in selectivity in both modes of reaction is discussed. By contrast, platinum catalyzes the transformation of methanol to dimethyl ether with high selectivity.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00764106
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