ISSN:
0947-3440
Keywords:
Thiols
;
Transannular additions
;
Sulfur
;
Radical Reactions
;
Polar Reactions
;
Cage compounds
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
As an example of system A, compound 5 was reacted with several thiols. A radical route procedures transannular 1,4-addition products (6a/b). In the presence of sulfur, the addition reaction is strongly enhanced, and a polar route yields 1,2-adducts (7a/b). Structures 6a/b and 7a/b are supported by X-ray analysis. The different reaction modes are discussed.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970424
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