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  • 1
    ISSN: 1432-0517
    Keywords: Key words Trace elements ; Water ; Intercomparison ; Comparability ; Traceability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  The sixth round of the International Measurement Evaluation Programme (IMEP) is presented. The programme offers reference values, established by primary methods of measurement, against which participating laboratories can evaluate their performance. The degree of comparability is thus established against the most objective references available at present. In IMEP-6, reference values for total concentrations of 14 trace elements in a synthetic and a natural water were established mainly by isotope dilution mass spectrometry (IDMS). For the majority of the measurands, results traceable to the international system of units (SI) and having expanded uncertainties, U (k=2), of 2% could be established. Measurements results from 165 field laboratories in 29 countries are evaluated and presented as descriptive (regional, national and intercontinental) pictures of the participants' self-declared degree of experience, status of accreditation, performance (including target values for uncertainty set by authorities) and instrumental methods used. The participants' use of certified reference materials and calibrants has been documented, and some comments on this matter are raised. The results and characteristics for IMEP-6 are compared with those of IMEP-3 (1991–1993) and discussed in view of the forthcoming IMEP-9 (1998).
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0517
    Keywords: Key words Comparability ; Traceability ; Isotope-specific methods ; Isotope dilution mass spectrometry ; Neutron-activation analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  In the seventh round of the Institute for Reference Materials and Measurements' International Measurement Evaluation Programme, 277 clinical laboratories from 17 countries participated. The measurands consisted of inorganic components, present at minor and trace level, in a human liquid serum. Results for calcium, chloride, copper, magnesium, sodium, selenium and zinc are reported and are compared to reference values established mainly by isotope dilution mass spectrometry and neutron-activation analysis. The overall conclusion is that routine measurements of total concentrations of the components by clinical laboratories are of high quality. The fraction of significant errors is small (0.5%) and the self-declared uncertainty values are generally fairly realistic. Results are further commented on with respect to the recent development in metrology in chemistry.
    Type of Medium: Electronic Resource
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