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Synthesis and characterization of SnOx/Al2O3 derived gel catalysts (1996)

Gomez, Ricardo ; Sanchez, Jaime ; Silva, Rebeca ; [et al.]

Springer

Reaction kinetics and catalysis letters 59 (1996), S. 247-251

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ISSN: 1588-2837

Keywords: Tin-alumina support ; sol-gel derived alumina ; isopropanol dehydration ; tin-alumina acidity

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract SnOx/Al2O3 catalysts were prepared by the sol-gel method using as starting reactants aluminium-tri-s-butoxide and (i) tetrabutyltin, (ii) tin tetrachloride and (iii) tin tetra-t-amyloxide. The gel derived catalysts show acidities of 0.72, 1.08 and 1.05 μmol NH3/m2 and BET areas of 91, 112 and 189 m2/g. The activity and selectivity pattern for isopropanol decomposition were found to depend strongly on the tin precursor used.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02068120

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