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Electronic Communication in [Co2(CO)6]2-Diyne and [Co2(CO)4(dppm)]2-Diyne Complexes (1998)

Osella, Domenico ; Milone, Luciano ; Nervi, Carlo ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1473-1477

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ISSN: 1434-1948

Keywords: Electrochemistry ; Mixed-valent compounds ; Alkynecobalt complexes ; Through-bond interactions ; Through-space interactions ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The electrochemical behaviour of the [Co2(CO)6]2(μ-R-C≡C-L-C≡C-R) and [Co2(CO)4(dppm)]2(μ-R-C≡C-L-C≡C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.

Type of Medium: Electronic Resource

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