ISSN:
0935-6304
Keywords:
Supercritical fluid chromatography
;
Three-dimensional diagrams
;
Selectivity
;
Effective plate height
;
Temperature dependence
;
Pressure dependence
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The dependence of the selectivity α and the effective plate number, N, on temperature and pressure is shown in three-dimensional diagrams. The specific system studied was pentane as the mobile phase, unmodified silica as the stationary phase, and a set of four polycyclic hydrocarbons as the test mixture. Temperature and pressure ranges were from 25 to 300°C and from 30 to 75 bar, respectively. The plots for α and N are found to resemble those for capacity ratio, k′, and resolution, R, studied earlier with the same system [1]. A distinct maximum is observed for N in the supercritical region, as found earlier for k′ and R. This applies also to α for the homologous substrate pair naphthalene/anthracene, while the resemblance for α is less pronounced for the pair anthracene/pyrene.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240100307
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