Electronic Resource
Weinheim
:
Wiley-Blackwell
Angewandte Chemie International Edition in English
8 (1969), S. 482-492
ISSN:
0570-0833
Keywords:
Thiiranium ions
;
Sulfenyl chlorides
;
Sulfur
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The addition of sulfenvl chlorides or sulfur dichloride to unsaturated compounds proceeds via thiiranium ions. The present article reviews the electronic and steric factors influencing the nature of these ions and their effects on subsequent ring opening and product formation. For the purpose of this discussion results primarily from electrophilic ring opening have been chosen to illustrate these factors. Solvent and temperature effects have been disregarded.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196904821
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