ISSN:
1573-1111
Schlagwort(e):
UV-visible spectra
;
charge transfer complex
;
formation constant
;
DB18C6
;
TCNE
;
DDQ
;
halides
;
electron transfer
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The UV-Visible spectra of DB18C6 as a donor with TCNE (Tetracyanoethylene), and DDQ (2,3-dichloro-5,6-dicyano-1,4- benzoquinone) as acceptors were studied. Charge transfer spectra were obtained for these systems from which it was possible to calculate the formation constant, Kc. The effects of potassium halides were studied. This study shows that in the presence of the anion there is an electron transfer from the anion to the acceptor. This process is enhanced by the presence of the crown ether, CE. The formation of the anion salt with the acceptor, in the presence of the CE, follows the trend F = I 〉 Br 〉 Cl. It is also indicated in this study that the interaction between DB18C6 and the acceptor follow the trend DDQ 〉 TCNE.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1008096210619
Permalink
