ISSN:
0570-0833
Keywords:
Phase-transfer catalysis
;
Catalysis
;
Synthetic methods
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Quaternary ammonium and phosphonium salts catalyze reactions between substances located partly in an aqueous and partly in an organic phase. Use of such phase-transfer catalysts simplifies and accelerates numerous reactions traditionally conducted in nonaqueous media. These reactions include carbene reactions, nucleophilic substitutions, alkylations of ketones and nitriles, Wittig and Darzens reactions, formation of ethers and esters. Other reactions such as hydrolysis and oxidation can be accelerated.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.197401701
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