ISSN:
1434-1948
Keywords:
Iridium
;
Amphiphiles
;
N ligands
;
Structure elucidation
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of 4′-functionalized 6′-phenyl-2,2′-bipyridine ligands (L-n) with the dimer [(ppy)2IrCl]2 (ppy = 2-phenylpyridine anion) and subsequent counterion exchange affords a new series of cationic orthometallated iridium(III) complexes, [(ppy)2Ir(L-n)][PF6] (1-5), which have been characterized by spectroscopic methods. These complexes have a large shape anisotropy and significant amphiphilic character. The crystal structure of 4 has been determined by X-ray diffraction.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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