ISSN:
1572-9001
Keywords:
Structural modeling
;
intercalated compounds
;
powder diffraction
;
α-zirconium phosphate derivates
;
copper complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Reasonable structural models are proposed for the Cu complexes of two intercalated compounds of α-Zr(HPO4)2·H2O (α-ZrP): one with 1,10-phenanthroline (A) and the other with 2,2′-bipyridyl (B). The models are derived from considerations of the unit-cell geometry changes undergone by α-ZrP upon insertion of, first, the organic molecules and then copper, in accordance with a set of general criteria of structural analysis called the “comparison method.”
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02278691
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