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  • General Chemistry  (5)
  • Strontium  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 592 (1991), S. 73-78 
    ISSN: 0044-2313
    Keywords: Sr8Co6O15Cl4 ; Oxohalogeno Metallate ; Strontium ; Cobalt ; Oxygen ; Chlorine ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On an Oxide Chloride of CoIII: Sr8Co6O15Cl4Sr8Co6O15Cl4 was prepared for the first time by flux reaction. It crystallizes with tetragonal symmetry: space group D4h17-I4/mmm; a = 3.927; c = 31.429 Å; Z = 1. Co3+ has different coordinations. One point position show CoO6 octahedra, the other one has a CoO5Cl surrounding. An oxygen deficit exhibit partly distorted square pyramids. Sr8Co6O15Cl4 is strongly related to Ba8In6O17.5 or can be seen as Sr4Co3O7.5Cl2 as a variety of the Sr4Ti3O10 type.
    Notes: Sr8Co6O15Cl4 wurde erstmals mit einer Schmelzmitteltechnik dargestellt. Es kristallisiert tetragonal: Raumgruppe D4h17-I4/mmm; a = 3,927; c = 31,429 Å; Z = 1. Co3+ ist unterschiedlich koordiniert. Eine Punktlage weist eine oktaedrische CoO6-, die zweite eine CoO5Cl-Umgebung auf. Bedingt durch ein Sauerstoffdefizit treten im Mikrobereich tetragonale CoO5-Pyramiden auf. Sr8Co6O15Cl4 ist eng mit Ba8In3O17,5 verwandt, oder kann in der Schreibweise Sr4Co3O7,5Cl2 als Variante des Sr4Ti3O10-Typs angesehen werden.
    Additional Material: 1 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 594 (1991), S. 127-132 
    ISSN: 0044-2313
    Keywords: Strontium ; Copper ; Vanadium ; Crystal Chemistry ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On a Second Alkaline Earth-Copper Oxovanadate: SrCuV2O7Single crystals of SrCuV2O7 were prepared by solid state reaction in the order of the meltingpoint of the component mixture. The yellowgreen crystals have orthorhombic symmetry, space group D2h16-Pnma; a = 14.470; b = 5.470; c = 7.420 Å; Z = 4. SrCuV2O7 represent a new crystal structure with V5+ in tetrahedric coordination, forming V2O7-double-tetrahedra, which are connected with CuO5 square pyramids into planes. Sr2+ between these planes has a complicated surrounding of 11 O2-. The structure is discussed with respect to the not isotypic compound CaCuV2O7.
    Notes: Einkristalle von SrCuV2O7 wurden durch Feststoffreaktion im Bereich des Schmelzpunktes der Reaktionsmischung erhalten. Die gelbgrünen Kristalle haben orthorhombische Symmetrie, Raumgruppe D2h16-Pnma; a = 14,470; b = 5,470; c = 7,420 Å; Z = 4. SrCuV2O7 repräsentiert eine neue Kristallstruktur, die V5+ in tetraedrischer Koordination zeigt. Es treten isolierte V2O7-Tetraederdoppel auf, die mit CuO5-Pyramiden in Ebenen verknüpft sind. Sr2+ hat eine komplizierte Umgebung von 11 O2-. Die Struktur wird mit der nicht isotypen Verbindung CaCuV2O7 diskutiert.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 611 (1992), S. 137-140 
    ISSN: 0044-2313
    Keywords: Barium ; Strontium ; Thallium ; Oxides ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On BaTiVO4 and SrTiVO4BaTiVO4 and SrTiVO4 were prepared in closed systems by solid state reactions. They crystallize with orthorhombic symmetry (BaTiVO4: space group D2h16-Pmnb; a = 5.889; b = 7.889; c =10.397 Å; Z = 4; SrTiVO4: space group D24-P21,21,21,21; a = 5.855; b = 7.572; c = 10.012 Å; Z = 4) and belong to β-K2SO4-type. The ordered occupation of point positions by Ba2+ and Tl+ as well as the decrease in symmetry of SrTiVO4 are discussed.
    Notes: BaTiVO4 und SrTiVO4 wurden durch Festkörperreaktionen im geschlossenen System dargestellt. Beide Verbindungen Kristallisieren orthorhombisch (BaTiVO4: Raumgruppe D2h16-Pmnb; a = 5,889; b = 7, 889; c = 10,397; Å; SrTiVO4: Raumgruppe D24-P21,21,21,; a= 5,855; b = 7,572; c = 10,012 Å; Z = 4) und stellen Varianten des β-K2SO4-typs dar. Die geordnete Besetzung der Punktlagen mit Ba2+ und Tl+ sowie die Symmetrieerniedrigung in SrTiVO4 werden diskutiert.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 618 (1992), S. 39-42 
    ISSN: 0044-2313
    Keywords: Strontium ; Bismuth ; Vanadium ; Oxide ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Sr2Bi3V3O14Single crystals of the hitherto unknown compound Sr3Bi3V3O14 were prepared and investigated by X-ray work. It crystallizes with triclinic symmetry, space group P1, a = 7.0838, b = 7.1732, c = 14.1067 Å; α = 97.46, β = 98.70, γ = 110.99°, Z = 2. The crystal structure is characterized by VO4 tetrahedra and one side open Bi3+ coordination inside Bi2O11 groups.
    Notes: Die bisher unbekannte Verbindung Sr2Bi3V3O14 wurde einkristallin dargestellt und röntgenographisch untersucht. Sie kristallisiert triklin, in der Raumgruppe P1 mit a = 7,0838, b = 7,1732, c = 14,1067 Å; α = 97,46, β = 98,70, γ = 110,99°, Z = 2. Die Kristallstruktur ist durch VO4-Tetraeder und Bi2O11-Einheiten mit einseitig offener Bi3+-Koordination ausgezeichnet.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 77 (1965), S. 1088-1088 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 82 (1970), S. 139-139 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 88 (1976), S. 345-345 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 9 (1970), S. 174-174 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 15 (1976), S. 319-319 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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