ISSN:
0392-6737
Keywords:
Experimental determinations of smectic, nematic, cholesteric, and lyotropic structures
;
Specialized material fabrications and fabrication techniques
;
Conference proceedings
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Summary Pattern formation at phase boundaries moving in a temperature gradient is one of the major areas of nonequilibrium physics attracting considerable attention. While most of the early work concentrated on the moving solid-liquid interface, now the focus has changed to phase transitions characterized by broken continuous symmetry. Most recently we investigated consequences to interfacial patterns of a chirality-induced equilibrium length. Here we study patterns at another chiral interface where one of the phases has a chirality-induced defect lattice, the twist grain boundary (TGB) phase. The TGB state is analogous to the vortex lattice in Type-II superconductors predicted by the Gennes’ analogy between the nematic (N)-smectic A (A) transition and the normal-superconducting transition. In this analogy, a cholesteric A transition is analogous to the normal-superconducting transition in an external magnetic field and a theory has been developed for its analogous vortex lattice, the TGB phase, when this transition is Type II. We study patterns formed at the traveling TGB-A phase boundary. Different patterns are observed depending on whether TGB grows into A or A into TGB. Indeed, this maybe the first time a steady-state pattern is observed in directional melting (i.e. TGB growing into A). As these patterns have a broad band of wavelengths, they are difficult to characterize physically. Thus, we introduced a novel analysis (most simply but not rigorously described as) measuring the fractal dimension of the patterns at these traveling interfaces. Two lengths emerged from this analysis: a longer one set by sample thickness and a shorter one set by the smallest TGB unit that can grow into an oriented smectic A phase. We invoke our old dynamic arguments to account for why TGB cannot propagate at a second-order TGB-cholesteric phase transition so it is eventually squeezed out leaving behind a direct cholesteric-A transition.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02456722
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